Hydrodeoxygenation and hydrogenolysis of biomass-based materials using FeNi catalysts and magnetic induction

Marín, Irene Mustieles; Masi, Déborah De; Lacroix, Lise‐Marie; Leeuwen, Piet W. N. M. van; Asensio, Juan M.; Chaudret, Bruno

doi:10.1039/d0gc03495a

Cited by 46 publications

(42 citation statements)

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“…Another aspect that we have not explored in this Perspective but that we expect will develop in the coming years is the possibility of combining physical and chemical properties in a single entity to address the onset of catalytic reactions by an external optical or magnetic stimulus. We are presently engineering FeC x @Ru, FeCo@C, and FeNi 3 @Ni NPs for CO 2 methanation, methane dry re-forming, or hydrodeoxygenation of biomass platform molecules in solution in mild conditions . Here, all the phenomena of alloying, dealloying, and oxidation that we have highlighted in this Perspective can be present and can participate in the catalysis under the magnetic stimulus. − …”

Section: Magnetic Propertiesmentioning

confidence: 99%

“…We are presently engineering FeC x @Ru, FeCo@C, and FeNi 3 @Ni NPs for CO 2 methanation, methane dry re-forming, or hydrodeoxygenation of biomass platform molecules in solution in mild conditions . Here, all the phenomena of alloying, dealloying, and oxidation that we have highlighted in this Perspective can be present and can participate in the catalysis under the magnetic stimulus. − …”

Section: Magnetic Propertiesmentioning

confidence: 99%

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Bimetallic Nanoparticles Associating Noble Metals and First-Row Transition Metals in Catalysis

2021

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Bimetallic nanoparticles (NPs) are complex systems with properties that far exceed those of the individual constituents. In particular, association of a noble metal and a first-row transition metal are attracting increasing interest for applications in catalysis, electrocatalysis, and magnetism, among others. Such objects display a rich structural chemistry thanks to their ability to form intermetallic phases, random alloys, or core-shell species. However, under reaction conditions, the surface of these nanostructures may be modified due to migration, segregation, or isolation of single atoms, leading to the formation of original structures with enhanced catalytic activity. In this respect, Zakhtser et al. report in this issue of ACS Nano the synthesis and study of the chemical evolution of the surface of a series of PtZn nanostructured alloys. In this Perspective, we report some selected examples of bimetallic nanocatalysts and their increased activity compared to the corresponding pure noble metal, with a special focus on Pt-based systems. We also discuss the mobility of the species present on the catalyst surface and the electronic influence of one metal to the other. Bimetallic nanocrystals, which comprise a noble metal (in particular, a platinum group metal) and a non-noble metal (in general, a first-row transition metal), are attracting a lot of interest because of

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Section: Magnetic Propertiesmentioning

confidence: 99%

Section: Magnetic Propertiesmentioning

confidence: 99%

Bimetallic Nanoparticles Associating Noble Metals and First-Row Transition Metals in Catalysis

2021

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“…Recently, bimetallic FeNi 3 NPs enriched with Ni (FeNi 3 @Ni) have been used as catalysts as well as magnetic heating agents for the oligomerization of CPN to yield C 10 and C 15 oligocyclopentyl products. 115 Cycloalkanes were produced in two steps in ∼84.8% overall carbon yield starting from CPN and FF. 116 In the initial step, 2,5-di(furylmethyl)cyclopentanone (DFMCPN) was prepared in a 98.5% yield by the aldol condensation/hydrogenation reaction of CPN and FF using Pd/C–CaO as a solid bifunctional base as well as a hydrogenation catalyst.…”

Section: Applications Of Cpn and Hcpnmentioning

confidence: 99%

Catalytic Transformation of Biomass-Derived Furfurals to Cyclopentanones and Their Derivatives: A Review

Dutta

Bhat

2021

ACS Omega

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Furfural (FF) and 5-(hydroxymethyl)furfural (HMF) are well-recognized biomass-derived chemical building blocks with established applications and markets for several of their derivatives. Attaining a wide spectrum of petrochemicals is the primary target of a biorefinery that employs FF and HMF as the chemical feedstock. In this regard, cyclopentanone (CPN) is a crucial petrochemical intermediate used for synthesizing a diverse range of compounds with immense commercial prospects. The hydrogenative ring rearrangement of FF to CPN in an aqueous medium under catalytic hydrogenation conditions was first reported in 2012, whereas the first report on the catalytic conversion of HMF to 3-(hydroxymethyl)cyclopentanone (HCPN) was published in 2014. Over the past decade, several investigations have been undertaken in converting FF and HMF to CPN and HCPN, respectively. The research studies aimed to improve the scalability, selectivity, environmental footprint, and cost competitiveness of the process. A blend of theoretical and experimental studies has helped to develop efficient, inexpensive, and recyclable heterogeneous catalysts that work under mild reaction conditions while providing excellent yields of CPN and HCPN. The time is ripe to consolidate the data in this area of research and analyze them rigorously in a review article. This work will assist both beginners and experts of this field in acknowledging the accomplishments to date, recognize the challenges, and strategize the way forward.

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“…[1] Attempts were also made to exploit the benefits associated with magnetic induction in heterogeneous catalysis. [2] More recently,small magnetic nanoparticles heated by magnetic induction were used either as heating agents or directly as catalysts to effectively activate chemical transformations in the gas phase (e.g., Fischer-Tropsch, [3] CO 2 methanation, [4] propane dehydrogenation, [4e] methane steam reforming [5] )a sw ell as in solution (e.g., hydrogenation, [6] amidation, [7] water splitting, [8] hydrogenolysis [9] ). Under magnetic induction, the heat required to unlock catalytic activity is generated directly by the magnetic nanocatalysts (Figure 1).…”

Section: Introductionmentioning

confidence: 99%

Commercial Cu₂Cr₂O₅Decorated with Iron Carbide Nanoparticles as a Multifunctional Catalyst for Magnetically Induced Continuous‐Flow Hydrogenation of Aromatic Ketones

et al. 2021

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Copper chromitei sd ecorated with iron carbide nanoparticles,producing amagnetically activatable multifunctional catalytic system. This system (ICNPs@Cu 2 Cr 2 O 5 )c an reduce aromatic ketones to aromatic alcohols when exposed to magnetic induction. Under magnetic excitation, the ICNPs generate locally confined hot spots,s electively activating the Cu 2 Cr 2 O 5 surface while the global temperature remains low ( % 80 8 8C). The catalyst selectively hydrogenates as cope of benzylic and non-benzylic ketones under mild conditions (3 bar H 2 ,heptane), while ICNPs@Cu 2 Cr 2 O 5 or Cu 2 Cr 2 O 5 are inactive when the same global temperature is adjusted by conventional heating. Af low reactor is presented that allows the use of magnetic induction for continuous-flowh ydrogenation at elevated pressure.The excellent catalytic properties of ICNPs@Cu 2 Cr 2 O 5 for the hydrogenation of biomassderived furfuralacetone are conserved for at least 17 ho n stream, demonstrating for the first time the application of am agnetically heated catalyst to ac ontinuously operated hydrogenation reaction in the liquid phase.

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Hydrodeoxygenation and hydrogenolysis of biomass-based materials using FeNi catalysts and magnetic induction

Abstract: Bimetallic FeNi3 nanoparticles (NPs) enriched with Ni (FeNi3@Ni) have been used to perform the hydrodeoxygenation (HDO) and the cleavage of lignocellulose-derived products in solution using magnetic induction. The application of...

Cited by 46 publications

References 54 publications

Bimetallic Nanoparticles Associating Noble Metals and First-Row Transition Metals in Catalysis

Bimetallic Nanoparticles Associating Noble Metals and First-Row Transition Metals in Catalysis

Catalytic Transformation of Biomass-Derived Furfurals to Cyclopentanones and Their Derivatives: A Review

Commercial Cu₂Cr₂O₅Decorated with Iron Carbide Nanoparticles as a Multifunctional Catalyst for Magnetically Induced Continuous‐Flow Hydrogenation of Aromatic Ketones

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Hydrodeoxygenation and hydrogenolysis of biomass-based materials using FeNi catalysts and magnetic induction

Abstract: Bimetallic FeNi3 nanoparticles (NPs) enriched with Ni (FeNi3@Ni) have been used to perform the hydrodeoxygenation (HDO) and the cleavage of lignocellulose-derived products in solution using magnetic induction. The application of...

Cited by 46 publications

References 54 publications

Bimetallic Nanoparticles Associating Noble Metals and First-Row Transition Metals in Catalysis

Bimetallic Nanoparticles Associating Noble Metals and First-Row Transition Metals in Catalysis

Catalytic Transformation of Biomass-Derived Furfurals to Cyclopentanones and Their Derivatives: A Review

Commercial Cu2Cr2O5Decorated with Iron Carbide Nanoparticles as a Multifunctional Catalyst for Magnetically Induced Continuous‐Flow Hydrogenation of Aromatic Ketones

Contact Info

Product

Resources

About

Commercial Cu₂Cr₂O₅Decorated with Iron Carbide Nanoparticles as a Multifunctional Catalyst for Magnetically Induced Continuous‐Flow Hydrogenation of Aromatic Ketones