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“…2). It is of interest that the A2-pyrazolin-5-one appears to be thermodynamically more stable than the A2-pyrazolin-4-one, which can be crudely rational- "hph -NaOH O x P h + Hz02 o&Ph heterocycles, and on their known conversion to parent alcohols (8). The most closely related hydroperoxide in the literature is 10 which was recently proposed as an intermediate arising from aerial oxidation of 11 (9).…”
Section: Resultsmentioning
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rupbmjkragerfmgwileyiopcupepmcmbcthiemesagefrontiersapsiucrarxivemeralduhksmucshluniversity-of-gavle
“…2). It is of interest that the A2-pyrazolin-5-one appears to be thermodynamically more stable than the A2-pyrazolin-4-one, which can be crudely rational- "hph -NaOH O x P h + Hz02 o&Ph heterocycles, and on their known conversion to parent alcohols (8). The most closely related hydroperoxide in the literature is 10 which was recently proposed as an intermediate arising from aerial oxidation of 11 (9).…”
Section: Resultsmentioning
“…In the case of benzaldehyde this would generate stilbene oxide (1). This brings us right into the old debate, still ongoing, 29 about the mechanism of the Wittig reaction, 30 i.e.…”
Section: Interaction Between Aldehydes and Tppmentioning
“…-+ 2H + ae AE I2 + ROH + H2O (1) 2Na2S2O3 + I2 ae AE 2NaI + Na2S4O6 (2) (5), where d is the density of the oil (g/mL).…”
Section: Rooh + 2imentioning
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“…The most recent review of the subject of autoxidation is by Frank (110). Ingraham & Corse (111) have reported that the autoxidation of chlorogenic acid, which is involved in the "browning" of vegetables, is first order with respect to each reactant and inversely proportional to the H+ concentration.…”
mentioning