Hollow Nanospheres Organized by Ultra-Small CuFe2O4/C Subunits with Efficient Photo-Fenton-like Performance for Antibiotic Degradation and Cr(VI) Reduction

Abstract

Hollow transition metal oxides have important applications in the degradation of organic pollutants by a photo-Fenton-like process. Herein, uniform, highly dispersible hollow CuFe2O4/C nanospheres (denoted as CFO/C-PNSs) were prepared by a one-pot approach. Scanning electron microscope (SEM) and transmission electron microscope (TEM) images verified that the CFO/C-PNS catalyst mainly presents hollow nanosphere morphology with a diameter of 250 ± 30 nm. Surprisingly, the photodegradation test results revealed that CFO/C-PNSs had an excellent photocatalytic performance in the elimination of various organic contaminants under visible light through the efficient Fenton catalytic process. Due to the unique hollow structure formed by the assembly of ultra-small CFO/C subunits, the catalyst exposes more reaction sites, improving its photocatalytic activity. More importantly, the resulting magnetically separable CFO/C-PNSs exhibited excellent stability. Finally, the possible photocatalytic reaction mechanism of the CFO/C-PNSs was proposed, which enables us to have a clearer understanding of the photo-Fenton mechanism. Through a series of characterization and analysis of degradation behavior of CFO/C-PNS samples over antibiotic degradation and Cr(VI) reduction, •OH radicals generated from H2O2 decomposition played an essential role in enhancing the reaction efficiency. The present work offered a convenient method to fabricate hollow transition metal oxides, which provided impetus for further development in environmental and energy applications. Highlights: Novel hollow CuFe2O4/C nanospheres were prepared by a facile and cost-effective method. CuFe2O4/C exhibited excellent photo-Fenton-like performance for antibiotic degradation. Outstanding photocatalytic performance was attributed to the specific hollow cavity-porous structure. A possible mechanism for H2O2 activation over hollow CuFe2O4/C nanospheres was detailed and discussed.

Recent Progress of MIL MOF Materials in Degradation of Organic Pollutants by Fenton Reaction

“…The advantages of photocatalysis and Fenton-like technology grant MILs a wide range of applications in the field of photo-Fenton. The photo-Fenton system is considered one of the most promising processing technologies because it is easy to operate without high temperature and pressure [74]. Zhang et al designed a novel catalyst a-Fe 2 O 3 /MIL-53(Fe), which had the advantages of thermodynamic stability of a-Fe 2 O 3 , appropriate bandgap width, and the synergism of atom/MOFs catalyst (Figure 12a) [75].…”