We report on the phase-matching properties of borate crystals of LiB3O5 (LBO), CsB3O5 (CBO), and CsLiB6O10 (CLBO) in vacuum–ultraviolet (VUV) light generation at around 190 nm. A new phase-matching property in the VUV spectral range for CBO grown from a self-flux solution was found to have better agreement with new Sellmeier's equations developed in our laboratory. A 189 nm output of 11.4 mW was produced in a CLBO with a conversion efficiency of 7.3% from 213 nm input. CLBO is suitable for VUV light generation around 190 nm with the present laser system.