Highly efficient immobilized PN3P-pincer iridium catalyst for dehydrogenation of neat formic acid

A Palladium Catalyst Supported on Boron-Doped Porous Carbon for Efficient Dehydrogenation of Formic Acid

“…For example, Huang’s group reported a ruthenium pincer complex immobilized on a fibrous silica nanosphere with good stability toward water, high pressures, and high temperatures in formic acid dehydrogenation [ 9 ]. An immobilized PN 3 P-Ir pincer catalyst supported onto a 3D fibrous silica nanosphere that contains a tetracoordinate aluminum site was further synthesized, exhibiting high TOF and TON [ 11 ]. Svetlana Ivanova’s group investigated the formic acid decomposition behavior of mono- and bimetallic Pd/Ru catalysts supported on graphitic C 3 N 4 in both liquid- and vapor-phase conditions [ 12 ].…”

Anchoring PdAg alloys on self-crosslinked carbon dots as efficient catalysts for formic acid dehydrogenation under ambient conditions

“…Recent investigations have revealed that Pd-based heterogeneous catalysts are typically promising for hydrogen release from FA even at room temperature with only CO 2 as a by-product. 14,15 The price of Pd is almost one-fourth of the price of Pt-based catalysts. At the same time, Pd shows excellent catalytic activity, especially in many hydrogenation and dehydrogenation reactions.…”