In this paper, we demonstrated AlGaN/GaN metal-insulator-semiconductor high-electron mobility transistors (MIS-HEMTs) with AlN gate dielectric grown by plasmaenhanced atomic layer deposition (PEALD). The high-quality interface of AlN/AlGaN/GaN MIS-HEMTs resulted in a very small threshold voltage (V th ) hysteresis and dispersion. Simultaneously, the MIS-HEMTs exhibited a high-peak transconductance of 289 mS/mm and a small V th shift of 0.8 V, while those for Al 2 O 3 /AlGaN/GaN metal-oxide-semiconductor HEMTs were 203 mS/mm and 5.2 V, respectively. Furthermore, analysis indicated that PEALD-grown AlN significantly reduced the interface charges at dielectric/III-N interface (from 1.2 × 10 13 to 8 × 10 12 cm −2 eV −1 for interface traps, and from 1.01 × 10 13 to 3.1 × 10 11 cm −2 for fixed charges) and improved channel transport properties (the full-width at half-maximum of channel transconductance increased from 0.9 to 2.7 V), compared with ALD-grown Al 2 O 3 , which could explain the differences of device characteristics.Index Terms-AlGaN/GaN, AlN, interface, metal-insulatorsemiconductor high-electron mobility transistors (MIS-HEMTs), plasma-enhanced atomic layer deposition (PEALD), transport properties.