The authors demonstrated that N , NЈ-ditridecyl-3,4,9,10-perylenetetracarboxylic diimide ͑PTCDI-C13͒ thin-film transistors ͑TFTs͒ exhibited high field-effect electron mobility of 2.1 cm 2 / V s by just annealing at an adequate temperature ͑140°C͒ after the TFT fabrications. While PTCDI-C13 formed c-axis oriented thin films, the thermal treatments improved crystallinity of the thin films as revealed by x-ray diffraction. The thermal treatment also affected thin-film morphologies; the morphologies changed from oval ball-like grains to flat and large tilelike grains, which had molecular height steps and whose size reached several micrometers.