High efficiency single-junction semitransparent perovskite solar cells

Roldán‐Carmona, Cristina; Malinkiewicz, Olga; Betancur, Rafael; Longo, Giulia; Momblona, Cristina; Jaramillo, Franklin; Camacho, Luis; Bolink, Henk J.

doi:10.1039/c4ee01389a

Cited by 279 publications

(244 citation statements)

References 52 publications

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“…[ 71 ] Roldán-Carmona et al used a 6 nm thick gold electrode and a LiF capping layer to protect the gold layer and reduce refl ection, obtaining a 6.4% PCE and a 29% AVT. [ 72 ] Cheng et al improved the transparency and conductivity of the transparent electrode by using a MoO 3 -Au-MoO 3 confi guration ( Figure 6 a). [ 73 ] MoO 3 helped to form a thin and uniform Au layer, leading to enhanced conductivity.…”

Section: Semitransparent Cellsmentioning

confidence: 99%

Advances in Perovskite Solar Cells

et al. 2016

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widely commercialized, but possiblities to increase their performance are limited, because nowadays the so-called balance of systems (BoS) cost of PV modules makes up most of the cost. [ 1 ] As much of the BoS scales with area, performance improvement seems the only way to decrease the cost of PV power further. Therefore, new PV cells are sought either to allow for higher effi ciencies than what is possible with Si PV without cost increase, or, as explained in section 3.4, to provide lowcost added effi ciency to Si PV. Emerging solar cells such as dye-sensitized, bulkheterojunction and quantum-dot solar cells can be fabricated via low-temperature solution processing, that holds promise for low-cost large scale application, but best power conversion effi ciencies (PCE) are half of, or less than that of the best commercial Si PV cells. [ 2 ] This is where perovskite solar cells enter, as for the fi rst time in PV history it is possible to produce high-effi ciency cells at low monetary and energy costs, with apparent ease of fabrication from earth-abundant, readily available raw materials. The PCE for perovskite solar cells has increased from 2.2% to 20.1% since 2006, showing an inviting vista of commercialization. [ 3,4 ] Perovskite solar cells are named after the crystal structure of the light absorbers, the structure of the mineral CaTiO 3 . Many compounds with ABX 3 stoichiometry take this structure, where A and B are 12-and 8-coordinates cations, respectively, and X is the anion. [ 4 ] Of the many ABX 3 only few are suitable to be efficient light absorbers for solar cells due to requirements such as appropriate bandgap for good light-harvesting ability, energy level/band alignment with contacting materials, long charge carrier lifetime, τ, and high mobility, µ. Perovskites generally have divalent anions, and the strong electrostatic bonding mostly makes their (high) bandgaps not suitable for solar PV. Mitzi et al. initiated using perovskites containing halides, ammonium cations and Sn 2+ in optoelectronic devices, which formed the basis for the development of perovskites for solar cells. [ 5 ] Here we will focus on such halide perovskites, together with one divalent (Pb 2+ ) and one monovalent (mostly CH 3 NH 3 + ) cation. The most effi cient halide perovskite solar absorbers consist of organic ammonium ions (CH 3 NH 3 + or NH = CHNH 3 + ), Pb 2+ and halide ions (I − , Br − ).[ 4 ] CH 3 NH 3 PbI 3 possesses broad and intense light absorption. It is an ambipolar semiconductor (can be n-or p-type), and its charge carriers can have long diffusion lengths and lifetimes, which allow excellent PCE for solar cells made with it. [3][4][5][6] Another advantage of perovskite absorbers is the low-temperature solution-processing ability, which helps

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Section: Semitransparent Cellsmentioning

confidence: 99%

Advances in Perovskite Solar Cells

et al. 2016

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“…It has been proved in our previous works [28][29][30][31] and other reports [32][33][34] that the ultrathin Ag film with a suited optical coupling layer could meet the requirements of a transparent electrode. Our simulations [28] about bifacial semitransparent PSCs have shown that the maximum possible current density of a device illuminated from the Ag side rapidly increases with the decreasing Ag thickness, while it gradually decreases for the reverse illumination direction from the ITO side.…”

Section: Introductionmentioning

confidence: 99%

Efficient Semitransparent Perovskite Solar Cells Using a Transparent Silver Electrode and Four-Terminal Perovskite/Silicon Tandem Device Exploration

Chen

Pang

Zhang

et al. 2018

Journal of Nanomaterials

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Four-terminal tandem solar cells employing a perovskite top cell and crystalline silicon (Si) bottom cell offer a simpler pathway to surpass the efficiency limit of market-leading single-junction silicon solar cells. To obtain cost-effective top cells, it is crucial to develop transparent conductive electrodes with low parasitic absorption and manufacturing cost. The commonly used indium tin oxide (ITO) shows some drawbacks, like the increasing prices and high-energy magnetron sputtering process. Transparent metal electrodes are promising candidates owing to the simple evaporation process, facile process conditions, and high conductivity, and the cheaper silver (Ag) electrode with lower parasitic absorption than gold may be the better choice. In this work, efficient semitransparent perovskite solar cells (PSCs) were firstly developed by adopting the composite cathode of an ultrathin Ag electrode at its percolation threshold thickness (11 nm), a molybdenum oxide optical coupling layer, and a bathocuproine interfacial layer. The resulting power conversion efficiency (PCE) is 13.38% when the PSC is illuminated from the ITO side and the PCE is 8.34% from the Ag side, and no obvious current hysteresis can be observed. Furthermore, by stacking an industrial Si bottom cell (PCE = 14.2%) to build a four-terminal architecture, the overall PCEs of 17.03% (ITO side) and 11.60% (Ag side) can be obtained, which are 27% and 39% higher, respectively, than those of the perovskite top cell. Also, the PCE of the tandem cell has exceeded that of the reference Si solar cell by about 20%. This work provides an outlook to fabricate high-performance solar cells via the cost-effective pathway.

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“…Together with the considerable efforts devoted to pursuing high efficiencies via improved crystallization of perovskite and searching for low-cost interface materials, 4,10-13 aesthetic semitransparent perovskite solar cells have been simultaneously receiving growing attention because of their specific application in transparent architectures, [14][15][16][17] such as windows, rooftops, greenhouses and other fashion elements. To achieve efficient semitransparent perovskite devices, both the anode and the cathode of the devices should be highly transparent and conductive in order to minimize the optical and resistance losses.…”

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confidence: 99%

“…To date, several studies have reported semitransparent perovskite solar cells, but most of these devices employed thin metal films (Al, Ag, Au) as top electrodes which were fabricated based on energy-intensive evaporation processes. [15][16][17] It is well known that, in addition to low-cost materials, the cost reduction of photovoltaic devices substantially depends on the ability to use high-throughput coating techniques in combination with roll-to-roll processing. 18 Despite its importance, however, less attention has been paid to the exploration of solution-processable transparent electrodes for perovskite solar cells.…”

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High-performance semitransparent perovskite solar cells with solution-processed silver nanowires as top electrodes

et al. 2015

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In this work, we report efficient semitransparent perovskite solar cells using solution-processed silver nanowires (AgNWs) as top electrodes. A thin layer of zinc oxide nanoparticles is introduced beneath the AgNWs, which fulfills two essential functionalities: it ensures ohmic contact between the PC 60 BM and the AgNWs and it serves as a physical foundation that enables the solution-deposition of AgNWs without causing damage to the underlying perovskite. The as-fabricated semitransparent perovskite cells show a high fill factor of 66.8%, V oc = 0.964 V, J sc = 13.18 mA cm −2 , yielding an overall efficiency of 8.49% which corresponds to 80% of the reference devices with reflective opaque electrodes.Inorganic-organic halide perovskite solar cells have recently emerged as a promising photovoltaic technology due to their high efficiencies and low-cost processing potential. [1][2][3][4] The exceptional optoelectronic properties of the perovskite crystals such as high carrier mobility and long charge diffusion length promise highly efficient charge separation. 5,6 These intriguing characteristics make perovskites ideal materials for photovoltaic applications. Since the first device demonstration in 2009, power conversion efficiency (PCE) of perovskite solar cells processed by both vacuum-deposition and solutionprocessing has surged to over 15%. 2,4,[7][8][9] The continuous and fast progress in the research related to perovskite solar devices has established them as a serious contestant to the traditional silicon-based panels.Together with the considerable efforts devoted to pursuing high efficiencies via improved crystallization of perovskite and searching for low-cost interface materials, 4,10-13 aesthetic semitransparent perovskite solar cells have been simultaneously receiving growing attention because of their specific application in transparent architectures, 14-17 such as windows, rooftops, greenhouses and other fashion elements. To achieve efficient semitransparent perovskite devices, both the anode and the cathode of the devices should be highly transparent and conductive in order to minimize the optical and resistance losses. To date, several studies have reported semitransparent perovskite solar cells, but most of these devices employed thin metal films (Al, Ag, Au) as top electrodes which were fabricated based on energy-intensive evaporation processes. [15][16][17] It is well known that, in addition to low-cost materials, the cost reduction of photovoltaic devices substantially depends on the ability to use high-throughput coating techniques in combination with roll-to-roll processing. 18 Despite its importance, however, less attention has been paid to the exploration of solution-processable transparent electrodes for perovskite solar cells. Carbon based materials have received much attention for use as conducting electrodes for perovskite solar cells, due to their low-cost and high stability. 14,19,20 For example, Li et al.have recently reported semitransparent perovskite solar cells using carbon nanotub...

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High efficiency single-junction semitransparent perovskite solar cells

Abstract: Semitransparent efficient methylammonium lead iodide perovskite based solar cells.

Cited by 279 publications

References 52 publications

Advances in Perovskite Solar Cells

Advances in Perovskite Solar Cells

Efficient Semitransparent Perovskite Solar Cells Using a Transparent Silver Electrode and Four-Terminal Perovskite/Silicon Tandem Device Exploration

High-performance semitransparent perovskite solar cells with solution-processed silver nanowires as top electrodes

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