Magnetic torque and heat capacity measurements on TPP͓Fe͑Pc͒͑CN͒ 2 ͔ 2 are reported. The torque curves for the magnetic field rotated within the ab plane have a fourfold symmetry, exhibiting inversions around 13 and 27 K. The heat capacity exhibits a broad peak around T = 16.5 K. By applying the magnetic field along the c axis, the maximum value of the heat capacity is enhanced below 20 K. These results, as well as the magnetic susceptibility, were analyzed by employing a numerical calculation based on the anisotropic Heisenberg model in one dimension. The analyses revealed that: ͑i͒ the peak in the magnetic-susceptibility data around 25 K is due to an antiferromagnetic short-range order ͑SRO͒ formation associated with d electrons, and ͑ii͒ electrons fall into an antiferromagnetic state below 13 K. The spin-flop field of electrons is approximately 80 kOe at 9 K.