Utilizing electrospun immiscible blend fibers of poly(butylene adipate) (PBA) and polystyrene (PS) andfollowing coating by the high glass transition temperature poly(4-tert-butylstyrene) (P4tBS), confined PBA specimens in nanometer space were effectively prepared. The effect of a physical confinement environment on the PBA crystallization behavior, polymorphism and crystal transformation was adequately investigated. For non-isothermal crystallization, the crystallization ability and melting of subsequent heat…
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