2010
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Abstract: Four novel complexes, {[Ni(4)(HEIDC)(4)(H(2)O)(8)].2H(2)O} (1), {[Mn(HEIDC)(4,4'-bipy)(0.5)(H(2)O)].H(2)O}(n) (2), [Mn(6)(EIDC)(4)(py)(H(2)O)(4)](n) (3), and {[Cd(2)(EIDC)(H(2)EIDC)(4,4'-bipy)(1.5)].H(2)O}(n) (4) (H(3)EIDC = 2-ethyl-1H-imidazole-4,5-dicarboxylic acid, 4,4'-bipy = 4,4'-bipyridine, and py = pyridine) have been hydro(solvo)thermally synthesized by fine control over synthetic conditions, such as solvent and pH value, and structurally characterized. It is shown through single-crystal X-ray diffract… Show more

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“…In previous studies, we have obtained aC a(II) complex based on 2-ethyl-1H-imidazole-4,5-dicarboxylate under hydrothermal conditions [5]. 2 Oformsdiscrete complexes in the crystal structure, consisting of one Mn(II) ion, two mono-deprotonated 2-ethyl-1H-imidazole-4,5-dicarboxy anions, two coordinate water molecules and three solvate water molecules. Each Mn(II) ion is six-coordinated in a distorted octahedral environment, formed by two oxygen atoms (O1,O1 i )and two nitrogen atoms(N1, N1 i )fromtwo 2-ethyl-4-carboxylato-5-carboxy-1H-imidazole ligands in the equatorial planea nd twoc oordinate waterm olecules in thea picals ites (symmetry code i: 1-x,1-y,1-z).…”
Section: Discussionmentioning
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“…In previous studies, we have obtained aC a(II) complex based on 2-ethyl-1H-imidazole-4,5-dicarboxylate under hydrothermal conditions [5]. 2 Oformsdiscrete complexes in the crystal structure, consisting of one Mn(II) ion, two mono-deprotonated 2-ethyl-1H-imidazole-4,5-dicarboxy anions, two coordinate water molecules and three solvate water molecules. Each Mn(II) ion is six-coordinated in a distorted octahedral environment, formed by two oxygen atoms (O1,O1 i )and two nitrogen atoms(N1, N1 i )fromtwo 2-ethyl-4-carboxylato-5-carboxy-1H-imidazole ligands in the equatorial planea nd twoc oordinate waterm olecules in thea picals ites (symmetry code i: 1-x,1-y,1-z).…”
Section: Discussionmentioning
“…-,and react with metal ions to form fascinating complexes with different structures and useful properties. As an important derivative of H 3 Imda,2 -ethyl-1H-imidazole-4,5-dicarboxylate has been rarely explored [2][3][4]. In previous studies, we have obtained aC a(II) complex based on 2-ethyl-1H-imidazole-4,5-dicarboxylate under hydrothermal conditions [5].…”
Section: Source Of Materialsmentioning
“…To explore the effect of 2-position substituents of imidazole for dominating the self-assembly of metal-organic networks, we synthesised another new analogue ligand of 2-ethyl-1H-imidazole-4,5-dicarboxylic acid (H 3 EIDA), to prepare novel MOFs. To the best of our knowledge, in contrast to the ligand H 3 MIA, coordination polymers with H 3 EIDA have been rarely reported so far [8][9][10][11][12][13][14]. Herein we report the hydrothermal synthesis and crystal structure of anew cobalt (II) complex incorporating H 3 - [14].T he Cd(II) complex crystallizes in Monoclinic, space group C2/c whereas the Co (II) complex belongs to the Triclinic, P1 space group.…”
Section: Discussionmentioning
“…In this work, the semi-rigid ligand, 2-[(1H-1,2,4-triazol-1-yl) methyl]-1H-imidazole-4,5-dicarboxylic acid (HL), was synthesized. Similar ligands, which differ only in the groups on the 2-position of the imidazole ring, such as 2-ethyl-1H-imidazole-4,5-dicarboxylic acid, 2-propyl-1H-imidazole-4,5-dicarboxylic acid (Wang et al, 2008;Meng et al, 2009;Zhang, Li et al, 2010;Zhang, Ma et al, 2010;Feng, et al, 2010), and 2-pyridinyl-1H-imidazole -4,5-dicarboxylic acid Chen et al, 2010;Jing et al, 2010), have been studied extensively. We report herein on the crystal structure of the title one-dimensional coordination polymer.…”
Section: Methodsmentioning