Flame retardant cotton fabrics treated with organophosphorus polymer

Abou‐Okeil, A.; El‐Sawy, S.M.; Abdel‐Mohdy, F.A.

doi:10.1016/j.carbpol.2012.12.008

Cited by 136 publications

(40 citation statements)

References 3 publications

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“…Partially studied [42][43][44][45][46][47][48][49] Nylon fabrics The nylon fabrics were dip-treated in a solution containing FR and crosslinker. MCC analyses showed a decrease of HRR, THR and HRC.…”

Section: Cottonmentioning

confidence: 99%

“…Abou-Okeil et al [44] exploited the bulk polymerization process of methacryloyloxyethylorthophosphortetraethyldiamidate monomer in the presence of benzoyl peroxide as radical initiator, for synthesizing polymer (31) exploiting a three-step reaction ( Figure 22). Cotton fabrics were dipped into aqueous solutions of polymer (31) at different concentrations, in the presence of a binder and a crosslinker.…”

Section: Flame Retardants As Polymer-additivesmentioning

confidence: 99%

“…Abou-Okeil et al [44] exploited the bulk polymerization process of methacryloyloxyethylorthophosphortetraethyl-diamidate monomer in the presence of benzoyl peroxide as radical initiator, for synthesizing polymer (31) exploiting a three-step reaction (Figure 22). Furthermore, vertical burning tests performed on the treated samples showed a reduction of the afterglow time and of the char length, without after-flame phenomena, as compared to the untreated fabric.…”

Section: Flame Retardants As Polymer-additivesmentioning

confidence: 99%

“…[ 44] cotton The fabrics were treated by immersion in an aqueous solution of the FR in the presence of a buffer and shrinking agent. LOI measurements showed an increase in LOI values with increases in the FR concentration.…”

Section: Cottonmentioning

confidence: 99%

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Recent Advances for Flame Retardancy of Textiles Based on Phosphorus Chemistry

2016

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This paper aims at updating the progress on the phosphorus-based flame retardants specifically designed and developed for fibers and fabrics (particularly referring to cotton, polyester and their blends) over the last five years. Indeed, as clearly depicted by Horrocks in a recent review, the world of flame retardants for textiles is still experiencing some changes that are focused on topics like the improvement of its effectiveness and the replacement of toxic chemical products with counterparts that have low environmental impact and, hence, are more sustainable. In this context, phosphorus-based compounds play a key role and may lead, possibly in combination with silicon-or nitrogen-containing structures, to the design of new, efficient flame retardants for fibers and fabrics. Therefore, this review thoroughly describes the advances and the potentialities offered by the phosphorus-based products recently developed at a lab-scale, highlighting the current limitations, open challenges and some perspectives toward their possible exploitation at a larger scale.

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Section: Cottonmentioning

confidence: 99%

Section: Flame Retardants As Polymer-additivesmentioning

confidence: 99%

Section: Flame Retardants As Polymer-additivesmentioning

confidence: 99%

Section: Cottonmentioning

confidence: 99%

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Recent Advances for Flame Retardancy of Textiles Based on Phosphorus Chemistry

2016

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“…Organophosphorus compounds, especially the major industrial compounds known as Proban and Pyrovatex, have been established as excellent flame retardants because they have positive effects on flame-retardant properties of cotton fabrics [14]. These flame retardants can phosphorylate C(6) of the glucose monomer, inhibiting the formation of levoglucosan and promoting the dehydration process, which accelerate the formation of an inorganic carbonaceous fire residue [15].…”

Section: Introductionmentioning

confidence: 99%

Combustion behaviors of cotton fabrics treated by a novel nitrogen- and phosphorus-containing polysiloxane flame retardant

Dong

Zhang

et al. 2015

J Therm Anal Calorim

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A novel flame-retardant agent, nitrogenand phosphorus-containing polysiloxane [(IB-co-N-MDPA)PDMS] was synthesized, and it was employed on cotton fabrics. Cone calorimeter testing showed that the treated cotton fabric with (IB-co-N-MDPA)PDMS became less flammable with longer time to ignition and lower value of HRR, THR, EHC and mass loss. Thermogravimetric analysis demonstrated that (IB-co-N-MDPA)PDMS improved the thermal and thermo-oxidative stability of cotton fabric with fewer flammable volatiles, and more char is produced during combustion. Scanning electron microscopy showed that the surface of treated cotton fabric after combustion was covered by a compact char layer which indicated that (IB-co-N-MDPA)PDMS favored the formation of char as evidenced by the FTIR of residues. Furthermore, EDS analysis results demonstrated that the concurrent presence of Si and P in flame retardant effectively enhance the flame retardancy of cotton fabric with the remarkable amount of Si and P elements that were still present on the surface of fibers after combustion.

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Synthesis of phosphorus‐containing flame‐retardant antistatic copolymers and their applications in polypropylene

Li¹,

Chen

Song

et al. 2014

J of Applied Polymer Sci

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By adjusting the molar ratios of antistatic monomer of octyl phenol ethylene oxide acrylate (denoted as AS), rigid monomer of methyl methacrylate (denoted as MMA), and flame-retardant monomer of 2-(phosphoryloxymethyl oxyethylene) acrylate (denoted as FR), a series of flame-retardant antistatic copolymers poly (octyl phenol ethylene oxide acrylate-co-methyl methacrylateco-phosphoryloxymethyl oxyethylene acrylate) (donated as AMF) were synthesized through radical polymerization. Among the obtained copolymers, two copolymers, AMF162 (the feed molar ratio of AS, MMA, and FR as 1 : 6 : 2) and AMF1104 (the feed molar ratio of AS, MMA, and FR as 1 : 10 : 4) with different concentrations were added into polypropylene (PP) to prepare PP-AMF162 and PP-AMF1104 series of composites. The thermal stability, limiting oxygen index, the antistatic property, and mechanical properties of PP composites were tested and analyzed. PP-AMF162 series composites have excellent antistatic effect. When the AMF162 content was equal to or <15 wt %, the impact strength of PP-AMF162 composites was higher than that of pure PP. The results indicated that copolymer AMF162 was a suitable flame-retardant and antistatic additive for PP.

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Flame retardant cotton fabrics treated with organophosphorus polymer

Cited by 136 publications

References 3 publications

Recent Advances for Flame Retardancy of Textiles Based on Phosphorus Chemistry

Recent Advances for Flame Retardancy of Textiles Based on Phosphorus Chemistry

Combustion behaviors of cotton fabrics treated by a novel nitrogen- and phosphorus-containing polysiloxane flame retardant

Synthesis of phosphorus‐containing flame‐retardant antistatic copolymers and their applications in polypropylene

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