Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

3
19
0

Year Published

2012
2012
2022
2022

Publication Types

Select...
6
1

Relationship

1
6

Authors

Journals

citations
Cited by 28 publications
(22 citation statements)
references
References 28 publications
3
19
0
Order By: Relevance
“…We previously also demonstrated the applicability of this method to the synthesis of dithiaporphyrin- and porphyrin N -oxide-based porpholactones. 17,18 As also shown previously, 6,10,11,12 additional metalloporpholactones are available through metal insertions into the free bases using standard methods (using conventional and microwave heating).…”
Section: Resultssupporting
confidence: 58%
See 2 more Smart Citations
“…We previously also demonstrated the applicability of this method to the synthesis of dithiaporphyrin- and porphyrin N -oxide-based porpholactones. 17,18 As also shown previously, 6,10,11,12 additional metalloporpholactones are available through metal insertions into the free bases using standard methods (using conventional and microwave heating).…”
Section: Resultssupporting
confidence: 58%
“…14,16-19,20 This reaction was adopted by other groups, providing a range of dihydroxychlorins. 10,11,21-23 We further demonstrated the versatility of the chlorin diols as starting material for the preparation of porphyrinoids containing non-pyrrolic building blocks using our versatile ‘breaking and mending’ strategy. 9,14-18,24,25 The synthesis of porpholactones via the MnO 4 − -mediated oxidation of the known meso -tetraaryl-2,3-dihydroxychlorins also follows this strategy.…”
Section: Introductionmentioning
confidence: 89%
See 1 more Smart Citation
“…36 Systematic variation of the oxidant: substrate molar ratio revealed the best compromise between catalytic activity and sulfoxide ee value (Table 4, note numbers in bold). The concentration of catalyst is an important factor, as previously reported by H. R. Khavasi et al 89 For all catalysts, the conversion of thioanisole increased when the proportion of catalyst was increased from 0.5 mol% to 1 mol% of substrate. A higher concentration of catalyst reduced conversion and ee value with almost no changes in sulfoxide selectivity (>89%) ( Table 5).…”
Section: Inuence Of Oxidant and Catalyst Concentrationssupporting
confidence: 65%
“…Along this line, metalloporphyrins have been used as biomimetic models for the cytochrome P450 enzyme under homogeneous conditions [6]. These compounds play an important role in the oxidation of alcohols [7][8][9], sulfides [10,11], epoxidation of alkenes [12,13], and hydroxylation of alkanes [14][15][16]. Indeed, the synthesis of metalloporphyrins is challenging, often with low yield and tedious workup procedures.…”
Section: Introductionmentioning
confidence: 99%