Ferrocene-containing macrocyclic triazoles for the electrochemical sensing of dihydrogen phosphate anion

Covalent Organic Helical Cages as Sandwich Compound Containers

“…Organometallic SCs may present reversible redox processes with low potentials. This characteristic has enabled their applicability in electrochemical sensing . The interest in continuous detection calls for the development of new sensing methodologies .…”

Crystal structure of 3-methyl-cyclobis(1-(1,1′-ferrocenylmethyl)-4-butyl-1H-1,2,3-triazole) tetrafluoroborate, C21H25FeN6⋅BF4

“…The dihedral angle between the planes defined by the triazole rings is 21.10(15) Å. In the ferrocene part, the iron atom is sandwiched almost perfectly centrally between the two cyclopentadienyl rings, with the Fe-C bond lengths in the range 2.012(7)-2.040(8) Å within the normal range [8]. The two cyclopentadienyl rings are not eclipsed, with the torsion angle of 13.7°.…”

Synthesis, Chiroptical, and Redox Properties of Ferrocene‐Containing Optically Active Polymers

“…Since its discovery in the 1950s, ferrocene has gathered much attention in the fields of polymer chemistry, supramolecular chemistry, and organometallic chemistry due to its reactivity and redox properties . Ferrocene derivatives containing various substituents including alkyl, vinyl, amino, and carboxy groups are utilized as key components of metal‐containing molecules and building blocks of macrocycles, metallacycles, and polymers . Ferrocene‐containing polymers are promising as functional materials applicable to memory devices, rechargeable lithium batteries, catalysts, and liquid crystalline materials .…”