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“…Compared to other TBT detection systems, it showed the widest range of response and one of the lowest LOD found in the literature [27,28]. The high sensitivity of this system is attributed to high selectivity of MIP implemented previously by Zhu et.al [19] and the high sensitivity of the EIS as reported before [29][30][31][32][33]. The results demonstrate that the MIP-Fe 3 O 4 NPs composite is a robust and stable receptor for the electrochemical detection of pesticides.…”
Section: Resultssupporting
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rupbmjkragerfmgwileyiopcupepmcmbcthiemesagefrontiersapsiucrarxivemeralduhksmucshluniversity-of-gavle
“…Compared to other TBT detection systems, it showed the widest range of response and one of the lowest LOD found in the literature [27,28]. The high sensitivity of this system is attributed to high selectivity of MIP implemented previously by Zhu et.al [19] and the high sensitivity of the EIS as reported before [29][30][31][32][33]. The results demonstrate that the MIP-Fe 3 O 4 NPs composite is a robust and stable receptor for the electrochemical detection of pesticides.…”
Section: Resultssupporting
“…Off-line SPE applications have also received attention. Methods include the in-situ extraction of organotins from water samples using dispersive molecularly imprinted polymers (MIPs), with isolation of TBT from water samples achieved using Fe 3 O 4 and molecularly imprinted templates [39,40]. SPME and liquid-phase microextraction (LPME) have received much interest [41], owing to their sensitivity, the reduction/elimination of harmful solvents and incorporation of simultaneous in-situ on-line extraction and derivatisation.…”
Section: Techniquesmentioning
“…The Freundlich (Chen, Xie, & Shi, 2013) and Langmuir (Zhu et al, 2013) isotherm models are often used for evaluation of the adsorption of the MIPs. The linear form of the Freundlich and Langmuir isotherm models are expressed by the following equations, respectively, where C free is equilibrium concentration of CLB (mg L À1 ), Q is amount of CLB adsorbed at equilibrium (mg g À1 ), Q max is maximum adsorption capacity (mg g À1 ), m is adsorption intensity or surface heterogeneity, a is adsorption capacity of CLB (mg g À1 ), K L is Langmuir adsorption equilibrium constant (L mg À1 ).…”
Section: Evaluation Of Static Adsorptionmentioning