The electrical conductance of 0.025 mol NaCl solution was measured at 0.25-3.75 GPa and 20-37013. As shown by the results, the conductance increases with temperature, and there is a liner relation between the reciprocal of temperature and the logarithm of the conductance but their slopes are different at different pressures. The relations between the conductance and pressure is rather complex and there are some discontinuities: in the range of 2.25-3.75 GPa, the conductance increases with the pressure; in the range of 1.25-2.0 GPa, the conductance is not related to the pressure; and at a pressure of 0.75 GPa, the conductance is higher than that at the pressures nearby. This reflects that the NaCl solution has rather different properties of electronic chemistry at various pressures, and probably is an important cause for the existence of the layers with high electrical conductance and low velocity in the Earth' s crust and mantle.A great amount of information obtained in studies of mineralogy, petrology and geochemistry indicates that the NaCI-H20 system is the most common system in the lithosphere. Therefore, the knowledge of the system at high temperatures and high pressures is important to the study of the origin of magma, formation of mineral deposits, evolution of continental crust and genetic mechanism of earthquakes.The study of electrical conductivity of water and aqueous NaCl solution at high temperatures and high pressures is one of the important methods to obtain the information of their properties. Since 1960, many investigators have carried out researches in this respect. However, most data were obtained from the experiments at pressures below 0.4 GPa (Holzapfel, 1969;Marshall and Franck, 1981;Tanger and Pitzer, 1989) and only a few at a pressure up to 1.0 GPa (Eberz and Franck, 1995;Ho et al., 1994) because of the limitation of the experimental equipment and insulate substances of the cell. Recently, we have carried out measurements of the electrical conductivity in a press fitted with a wedge-type cubic