The
effects of high-pressure shock waves generated by the detonation
of explosives are of major interest to the strategic sector. We report
interaction of transonic shock waves (1.1 Mach speed; peak pressure
>1.5 GPa) with graphene-like nanoflakes (GNFs). GNF samples, obtained
after chemical vapor deposition of a biomass, were studied using optical/electron,
force microscopy, Raman, and Brunauer–Emmett–Teller/Barrett–Joyner–Halenda
studies. Following this, GNF samples were subjected to high-strain-rate
measurements, using a split Hopkinson pressure bar technique to measure
variations in the stress, strain, and strain rate. Numerous dynamic
mechanical parameters are derived under a classical Lagrange–Rankian–Hugoniot
framework together with collecting statistics on the lateral flake
size, number of layers, defect density, wrinkle, slip characteristics,
etc. Broadly, the incident shock energy was dampened by ∼65%
of absorption loss with ∼15% transmittance. It has implications
on the GNF microstructure by reducing the flake squareness, area (by
∼50%), and exfoliating layer conjugation by around 5 times.
The in-plane impact was more profound compared to the out-of-plane.
Dislocation/slip dynamics showed significant modification in prismatic
loops (from buckled to ruck and tuck), with twinning exhibiting a
lowering of the Peierls–Nabarro stress to make disorder glissile.
At the molecular level, dynamic deformation dramatically modified
the force constants with bond elongation at −C–C–
by ∼80% and at −CC– by >150% compared
to pristine. An interactive model is presented.