2021
DOI: 10.1007/s11661-021-06142-7
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Experimental Investigation of Allotropic Transformation of Cobalt: Influence of Temperature Cycle, Mechanical Loading and Starting Microstructure

Abstract: The allotropic phase transformation in polycrystalline high-purity cobalt is incompletely reversible and exhibits a temperature hysteresis. This leads to the presence of a FCC metastable phase at room temperature, which alters the mechanical properties. Moreover this phase transformation seems to be able to be induced by the plastic deformation. The influence of thermal cycling and initial microstructure on the phase transformation has been analyzed with different experimental approaches namely in situ X-ray d… Show more

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Cited by 8 publications
(3 citation statements)
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“…The BCC phase volume fraction (denoted f BCC ) was determined, for each measurement point, using the Equation ( 1), as formulated by Bonarski et al [22] and used in previous works [23,24]…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…The BCC phase volume fraction (denoted f BCC ) was determined, for each measurement point, using the Equation ( 1), as formulated by Bonarski et al [22] and used in previous works [23,24]…”
Section: Methodsmentioning
confidence: 99%
“…The BCC phase volume fraction (denoted f BCC ) was determined, for each measurement point, using the Equation (1), as formulated by Bonarski et al [ 22 ] and used in previous works [ 23,24 ] fBCC=(1+IhklFCCIhklBCCRhklBCCRhklHCP)1$$f^{\text{BCC}} = \left(\left(\right. 1 + \frac{I_{\text{hkl}}^{\text{FCC}}}{I_{\text{hkl}}^{\text{BCC}}} \frac{R_{\text{hkl}}^{\text{BCC}}}{R_{\text{hkl}}^{\text{HCP}}} \left.\right)\right)^{- 1}$$where I hkl is the integrated intensity of the corresponding {hkl} peak and R hkl is the reflectivity of the lattice plane {hkl}, given by the following Equation (2) [ 22 ] Rhkl=1v2| Fhkl |2(1+cos2false(2θfalse)sin2false(2θfalse)cosfalse(θfalse))me2normalMμ$$R_{\text{hkl}} = \frac{1}{v^{2}} \left(\left|\right.…”
Section: Methodsmentioning
confidence: 99%
“…However, for very fine grains, it is believed that Co exists primarily in the FCC phase [10]. Additional factors affecting phase stability include strain [12], which, for bulk samples at room temperature, favors the conversion of any residual FCC phase to HCP [14]. The opposite behavior, however, is expected for nanocrystalline Co, which is predicted to undergo deformation via phase transformation from HCP to FCC, as the energy required for a phase transformation is lower than that required to generate twins [15].…”
Section: Cobalt Phasesmentioning
confidence: 99%