2018
DOI: 10.1016/j.corsci.2018.02.047
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Experimental and thermodynamic investigations on the chlorine-induced corrosion of HVOF thermal sprayed NiAl coatings and 304 stainless steels at 700 °C

Abstract: A B S T R A C TAlumina-forming β-NiAl coatings were deposited by high velocity oxy-fuel (HVOF) thermal spraying onto 304 stainless steels for protection against chlorine induced corrosion in a biomass-fired boiler. The corrosion test was conducted in a synthetic gas containing 500 ppm HCl with 10 wt% KCl ash deposit at 700°C for 250 h. Severe corrosion was observed with the fast growing alumina at the coating/substrate interface initiating from sample edges. Possible corrosion mechanism was proposed: as suppli… Show more

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Cited by 68 publications
(21 citation statements)
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“…Thermodynamic calculation of oxidation products as a function of effective partial pressures of O 2 at 900°C was carried out by Thermo-Calc Ò software (Version 2017b) with TCS Ni-based superalloys (TCNi8.1) database following CALPHAD (Computer Coupling of Phase Diagrams and Thermochemistry) ( Ref 27,28). The use of Thermo-Calc Ò on alumina-forming and chromia-forming alloys systems has been validated by our previous work (Ref 29,30) and others (Ref [31][32][33][34][35][36][37][38].…”
Section: Thermo-calc ò Calculationmentioning
confidence: 99%
“…Thermodynamic calculation of oxidation products as a function of effective partial pressures of O 2 at 900°C was carried out by Thermo-Calc Ò software (Version 2017b) with TCS Ni-based superalloys (TCNi8.1) database following CALPHAD (Computer Coupling of Phase Diagrams and Thermochemistry) ( Ref 27,28). The use of Thermo-Calc Ò on alumina-forming and chromia-forming alloys systems has been validated by our previous work (Ref 29,30) and others (Ref [31][32][33][34][35][36][37][38].…”
Section: Thermo-calc ò Calculationmentioning
confidence: 99%
“…However, under an air or simulated atmosphere of 600 • C, the Ni5Al coating has relatively low corrosion weight changes and corrosion product layer thickness [58,61,62]. With the increase in aluminum content, the corrosion resistance of NiAl(Ni31Al) coating has been improved under the condition in which the temperature is higher than 600 • C [24,49]. As shown in Figure 4, under the same conditions, they all show better corrosion resistance than NiCr coatings.…”
Section: Ni-based Coatingsmentioning
confidence: 98%
“…(a) Cross-sectional SEM micrograph (BSE) of the Ni5Al coating oxidized in 5% O 2 + 500 ppm HCl + N 2 for 168 h at 600 • C with KCl deposit[58]. (b) Cross-sectional BSE images of Ni31Al coating after corrosion at 700 • C for 250 h in synthetic gas with 500 ppm HCl and 10% KCl ash deposit[49].…”
mentioning
confidence: 99%
“…The corrosion problems related to biomass and waste-fired boilers have been reported to be mainly caused by Cl (Ref [7][8][9][10][11]. There are three corrosion mechanisms concerning the effect of Cl which are addressed in this review, including (…”
Section: Cl-induced Corrosionmentioning
confidence: 98%