Multiphysics manipulation of the exchange bias (EB) effect
to achieve
spin-valve-type spintronic device versatility has begun to attract
increasing attention recently. Light-controlled EB is considered to
be an attractive approach because the photon mode allows access to
a wide variety of materials with high speed, remote control, noncontact,
and superior resolution. In this work, we report a detailed photocontrolled
EB effect in the well-defined CoO@CoFePBA core–shell heteronanostructure,
where the EB effect of this composite can be permanently changed after
being exposed to light. As demonstrated, such an interesting photocontrolled
effect is actually affected by the composition of the CoFePBA shell.
More deeply, the alkali-metal-ion content in the CoFePBA shell is
the major factor in controlling these hybrids’ EB effects.
Different alkali-metal insertions result in different ratios of the
FeIII–CoII magnetic pair to the FeII–CoIII diamagnetic pair in the CoFePBA
shell, where FeIII–CoII and FeII–CoIII control the magnetic and photomagnetic effects
of CoFePBA, respectively. Therefore, the photocontrolled EB effect
of the whole nanohybrid can be adjusted by the amount of alkali-metal
insertion in the CoFePBA shell. This study is an advance in the research
of light-controlled EB effects, which are useful for the evolution
of new functional spintronic devices, such as photomagnetic switches,
photomagnetic sensors, and photointelligent information storage materials.