2008
DOI: 10.1016/j.electacta.2008.02.100
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Enzymes at solid surfaces: Nature of the interfaces and physico-chemical processes

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Cited by 30 publications
(27 citation statements)
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“…Common physico-chemical properties of metal substrata that could infl uence the settlement of organisms are their high surface energy and hydrophilicity. High surface energy of metal surfaces could promote adhesion, but is soon after immersion reduced by the adsorption of organic particles (KINLOCH 1990;CAILLOU et al 2008). Hydrophilicity of metal surfaces, as shown in several previous studies (PEDERSEN 1990;BECKER and WAHL 1991;BECKER 1996), makes adhesion of diatoms more diffi cult as opposed to adhesion on hydrophobic surfaces.…”
Section: Discussionmentioning
confidence: 99%
“…Common physico-chemical properties of metal substrata that could infl uence the settlement of organisms are their high surface energy and hydrophilicity. High surface energy of metal surfaces could promote adhesion, but is soon after immersion reduced by the adsorption of organic particles (KINLOCH 1990;CAILLOU et al 2008). Hydrophilicity of metal surfaces, as shown in several previous studies (PEDERSEN 1990;BECKER and WAHL 1991;BECKER 1996), makes adhesion of diatoms more diffi cult as opposed to adhesion on hydrophobic surfaces.…”
Section: Discussionmentioning
confidence: 99%
“…This difference may not be due to an orientation of the polymer segments at the surface, given the structure of the repeat unit [-CH 2 -CH(-NH-CH 3 )-] and the analyzed depth. It is attributed to the simultaneous presence at the surface of PAH and organic contaminants (Caillou et al, 2008). As the N/C ratio does not vary with , the adsorbed organic layer appears to be a mere mixture, with no preferential accumulation of a component at the outermost surface.…”
Section: Surface Conditioning With Pahmentioning
confidence: 94%
“…Both compounds are due to adventitious contamination which may originate from adsorption from air, as always observed for high surface energy solids (Caillou et al, 2008;Mantel et al, 1995), but also from aqueous media (Landoulsi et al, 2008a). They may be taken as a global way to reflect the amount of compounds which contain hydrocarbon chains and oxygen, such as esters, but excluding proteins and silane.…”
Section: Chemical Speciation Of the Organic Adlayermentioning
confidence: 99%
“…Moreover organic contaminants are always present on high energy solids. They are mainly of hydrocarbon nature and are readily adsorbed from surrounding air or in surface analysis spectrometers (Caillou et al, 2008;Landoulsi et al, 2008a). The possible influence of contaminants on the silanization process and product is usually not considered.…”
Section: Introductionmentioning
confidence: 99%