“…Pallach et al 21 report on the complex, entropy-driven phase change behavior of the alkoxy-functionalized MOF, MOF-5, which shows a temperature-and guest-responsive behavior as exemplified by the temperature-induced switching between a "dry," semi-/non-crystalline aperiodic structure and a highly crystalline cubic structure, driven by increased vibrational and conformational entropy. Kronawitter et al 22 identify the principles guiding the synthesis and glass forming properties of coordination polymers (CPs).…”