Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

5
176
0

Year Published

2017
2017
2022
2022

Publication Types

Select...
7
2

Relationship

1
8

Authors

Journals

citations
Cited by 224 publications
(181 citation statements)
references
References 54 publications
5
176
0
Order By: Relevance
“…Thus, after just one [Pd(hfac) 2 ]‐formalin ALD cycle on g‐C 3 N 4 (Pd 1 /g‐C 3 N 4 ), a Pd loading of 0.5 wt% is obtained. Aberration‐corrected HAADF‐STEM observations have shown that a high density of atomically dispersed Pd atoms was obtained on this support; neither Pd NP nor subnanometre clusters were observed at low or high magnifications. The six‐fold cavities on g‐C 3 N 4 are likely the anchoring sites for Pd atoms.…”
Section: Preparation Of Single Atom Catalystsmentioning
confidence: 86%
See 1 more Smart Citation
“…Thus, after just one [Pd(hfac) 2 ]‐formalin ALD cycle on g‐C 3 N 4 (Pd 1 /g‐C 3 N 4 ), a Pd loading of 0.5 wt% is obtained. Aberration‐corrected HAADF‐STEM observations have shown that a high density of atomically dispersed Pd atoms was obtained on this support; neither Pd NP nor subnanometre clusters were observed at low or high magnifications. The six‐fold cavities on g‐C 3 N 4 are likely the anchoring sites for Pd atoms.…”
Section: Preparation Of Single Atom Catalystsmentioning
confidence: 86%
“…According to DFT calculations, the performance of this SAC was rationalized considering the presence of electrodeficient Pd centres that allow: i) a facile and support‐assisted molecular hydrogen heterolytic dissociation; and ii) an easy (barrier‐less) coordination of the product that prevent over hydrogenation or oligomerization. In another report, Pd 1 /g‐C 3 N 4 exhibited much higher ethylene selectivity than Pd nanoparticles catalysts supported on the same material at near complete conversions of acetylene . Although the activity was lower, the coke formation on the single‐atom Pd 1 /g‐C 3 N 4 catalyst was largely suppressed in comparison with the other catalyst.…”
Section: Catalysis With Single Atom Catalysts On Carbon‐based Materialsmentioning
confidence: 95%
“…[5] Figure 1and Figure S7 show the high-angle annular dark-field scanning TEM (HAADF-STEM) images of samples.D ue to the different Z-contrast, [6] the darker spots (marked by red circles in Figure 1) surrounded by brighter spots (recognized as Ce atoms) can be identified as isolated Pd single atoms.T he intensity profiles (Figure 1b,c)i n different areas (Line 1a nd Line 2inF igure 1a,r espectively) further confirm the presence of isolated Pd 1 single atoms. [5] Figure 1and Figure S7 show the high-angle annular dark-field scanning TEM (HAADF-STEM) images of samples.D ue to the different Z-contrast, [6] the darker spots (marked by red circles in Figure 1) surrounded by brighter spots (recognized as Ce atoms) can be identified as isolated Pd single atoms.T he intensity profiles (Figure 1b,c)i n different areas (Line 1a nd Line 2inF igure 1a,r espectively) further confirm the presence of isolated Pd 1 single atoms.…”
mentioning
confidence: 99%
“…This material showed excellent activity and stability for both CO oxidation and preferential oxidation of CO in H 2 , which was attributed to the partially vacant 5d orbitals of positively charged and high‐valent Pt atoms. A number of SACs have been prepared subsequently, including various metal single atoms (SAs; Pt, Pd, Ir, Ru, Au, Co, Fe, et al) on various substrates such as metal oxides, nitrogen‐doped carbon, metal, and layered double hydroxides, with outstanding performance in diverse reactions such as hydrogenation, oxidation, and electrocatalysis …”
Section: Introductionmentioning
confidence: 99%