volume 117, issue 24, P12495-12501 2013
DOI: 10.1021/jp311185c
View full text
Andressa Mota, Markus Eiswirth, Ernesto R. Gonzalez

Abstract: Electrochemical reactions exhibit autosustained oscillatory states once the appropriate parameters are applied. As shown herein, the main impact of operating a reaction in an oscillatory state is the increased efficiency. The electroxidation of CO-containing hydrogen is analyzed because its oscillating mechanism mimics the oscillator known as hidden negative differential resistance (HNDR). With that, experimental results and the thermodynamic calculations of this contribution could be extended for other HNDR o…

expand abstract