Hydrogen, being a powerful energy carrier, possesses the ability to transform the present carbon economy to green hydrogen economy. Since wide range of resources are available for its production, reversible hydrogen storage is the prevalent challenge. Surface activation by adsorption has been reported to increase the hydrogen uptake, thus boosting the storage capacity. In this work, Sodium (Na) decorated Beryllonitrene (BeN 4 ) monolayer has been identi ed as a hydrogen storage material using rst-principles calculations. Our results reveal that Na decorated BeN 4 has ability to adsorb upto 12 H 2 molecules, leading to high gravimetric density of 4.26 wt%. The adsorption energy per H 2 (adsorbate) is moderate i.e., between 0.13 and 0.298 eV, good enough for hydrogen storage in practical applications. AIMD simulations disclose that adsorbate experiences no kinetic hinderance in desorption. Moreover, the desorption temperature of H 2 molecule on NaBeN 4 monolayer (substrate) varies from 162.5 to 382 K, con rming the reversibility of substrate and thus ensuring its potential for hydrogen storage medium. The short recovery time predicts that the substrate responds rapidly in presence of H 2 molecules, which guarantees the fast kinetics of adsorbate. Our calculations predict Na-decorated BeN 4 monolayer as an excellent candidate for reversible and high-capacity hydrogen storage material.