See inside back cover or msp.org/apde for submission instructions.The subscription price for 2013 is US $160/year for the electronic version, and $310/year (+$35, if shipping outside the US) for print and electronic. Subscriptions, requests for back issues from the last three years and changes of subscribers address should be sent to MSP.Analysis & PDE (ISSN 1948(ISSN -206X electronic, 2157 Let M be a scattering manifold, i.e., a Riemannian manifold with an asymptotically conic structure, and let H be a Schrödinger operator on M. One can construct a natural time-dependent scattering theory for H with a suitable reference system, and a scattering matrix is defined accordingly. We show here that the scattering matrices are Fourier integral operators associated to a canonical transform on the boundary manifold generated by the geodesic flow. In particular, we learn that the wave front sets are mapped according to the canonical transform. These results are generalizations of a theorem by Melrose and Zworski, but the framework and the proof are quite different. These results may be considered as generalizations or refinements of the classical off-diagonal smoothness of the scattering matrix for two-body quantum scattering on Euclidean spaces.