Electronic charge transport phenomena directed smart fabrication of Metal-Semiconductor based electronic junction device by a supramolecular Mn(II)-Metallogel

Structural Engineering and Electronic Properties of Halide-Specific Supramolecular Architectures: Effective for Stabilizing H5O2+and Fabricating Semiconducting Photoresponsive Diodes

“…The measured direct optical band gap from the obtained absorbance spectrum advocated that our fabricated complexes ( ITP-Cl and ITP-Br ) may possibly be employed as semiconductors. Subsequently, following the fabrication method employed in our previous work, − complex ( ITP-Cl and ITP-Br )-based very thin-film devices ( SD1 and SD2 along with complexes ITP-Cl and ITP-Br , respectively) with metal–semiconductor characteristics were constructed (details are provided in the Supporting Information) and studied for different charge-conducting electrical parameters by investigating the leading charge transport mechanisms. The current–voltage ( I–V ) plot of the designed devices SD1 and SD2 was documented under irradiation and non-irradiation conditions and is presented in Figure .…”

Itaconic and citraconic acid directed thixotropic and self-healable supramolecular metallogels of M(ii) (M = Co, Cu, Zn, and Cd) for the growth-inhibitory potency against human pathogenic microbes

“…22 Under the present research outlook, it is very urgent to unveil the significance of itaconic and citraconic acid not only in the soft-matter research but also in the aspects of metal ion-based functional constituents' formation. These two isomeric organic acid based soft gelscaffolds combined with the participating metal sources commonly known as metallogel, having diverse opportunities from biology to material science, [23][24][25][26][27][28][29][30][31][32][33] might be one of the cuttingedge directions to explore the utmost usefulness through its mechanically flexible constructions.…”

Establishment of different aliphatic amines-based rapid self-healing Mg(OH)2 metallogels: exploring the morphology, rheology and intriguing semiconducting Schottky diode characteristics

“…5 Powered by these, research with the high-end technical prospect of soft-scaffolds, applicable to the oil industry, 6 sensing purposes, 7 electro-optics and photonics, [8][9][10][11][12] makeup materials, 13 catalysis, 14 drug carriage, 15 and biomedical uses, 16 began its journey decades ago. Metal-ion-directed soft-matter like metallogels attracts special attention due to its functional versatility in terms of magnetism, 17 electronic features including semiconducting behaviour, [18][19][20][21][22][23][24] redox properties, 25 sensing applications, 26 catalysis, 27 energy materials, 28 nonlinear optical performance, 29 separation, 30 etc. The self-restoring feature of a metallogel is beneficial for providing several functionally advanced durable flexible materials that can be quickly self-recovered as a priority.…”