1993
DOI: 10.1063/1.464911
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Electron-temperature dependence of the recombination of H3O+(H2O)n ions with electrons

Abstract: The electron-temperature dependence of the recombination of H3O+(H2O)n cluster-ions with electrons has been measured in an afterglow experiment in which the electrons were heated by a radio-frequency electric field. The recombination coefficients were found to vary with electron temperature Te as ∼Te−1/2, in better agreement with theoretical expectations than earlier results of microwave-afterglow measurements.

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Cited by 50 publications
(49 citation statements)
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“…The rate constants of the DR reactions are on the order of ≈10 −5 –10 −8 cm 3 · s −1 depending on the electron temperature, size of water clusters and the gas pressure 32–34. Thus, the increase in the water level can partly explain the decrease of the electron density in DBD plasmas.…”
Section: Resultsmentioning
confidence: 99%
“…The rate constants of the DR reactions are on the order of ≈10 −5 –10 −8 cm 3 · s −1 depending on the electron temperature, size of water clusters and the gas pressure 32–34. Thus, the increase in the water level can partly explain the decrease of the electron density in DBD plasmas.…”
Section: Resultsmentioning
confidence: 99%
“…The temperature dependence of the recombination rate can be found by noting that the dominant positive ions in the lower ionosphere (z < 85 km) are water cluster ions H + (H 2 O) n . Their electron-ion recombination rate a depends on the number of water molecules in the cluster, with an average value given by [Gurevich, 1978;Johnsen, 1993] a ¼ a 0 300K=T e ð Þ 0:6 ; a 0 ¼ 2:5 Â 10 À6 cm 3 =s ð2Þ…”
Section: Efficiency Enhancement Physicsmentioning
confidence: 99%
“…Under these conditions the electron density initially decreases by a factor of ten through the dissociative recombination with O + 4 ions e + O + 4 → 2O 2 Figure 2. The rate coefficients for electron recombination with O + 2 [18], N + 2 [18], O + 4 [18] and H 3 O + (H 2 O) 3 [19] versus electron temperature.…”
Section: The Streamer In Long Air Gaps Under Standard Conditionsmentioning
confidence: 99%
“…The rate of electron recombination with H 3 O + (H 2 O) 3 ions is greater than that with O + 4 ions [18,19] (see figure 2). The acceleration of the plasma decay in the humid air decreases the conductivity of the streamer channel and as a consequence the electric field at the streamer head is reduced.…”
Section: The Effect Of Humiditymentioning
confidence: 99%