We have developed the electrochemical porosimetry analyzing microstructures of porous electrodes, which can give geometric information most meaningful in electrochemical systems. The methodology is based on the transmission line model with pore size distribution (TLM-PSD) that relates electrochemical impedance data with microstructural information. Pore length (l p ), as well as pore size distribution, can be obtained by fitting the TLM-PSD to the experimental impedance data of a porous electrode. This geomet…
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