Electrocatalytic Urea Synthesis via N<sub>2</sub> Dimerization and Universal Descriptor

Liu, Junxian; Lv, Xingshuai; Ma, Yandong; Smith, Sean C.; Gu, YuanTong; Kou, Liangzhi

doi:10.1021/acsnano.3c10451

Cited by 11 publications

(4 citation statements)

References 76 publications

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“…S4b†), but lower than those reported for several recent catalysts (0.74–1.41 eV). 72–75 Consequently, these Cu clusters demonstrate substantial urea electrosynthesis activity.…”

Section: Resultsmentioning

confidence: 98%

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo₂C MXene

Zhang,

Lu,

Zhao

et al. 2024

J. Mater. Chem. A

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“…S4b†), but lower than those reported for several recent catalysts (0.74–1.41 eV). 72–75 Consequently, these Cu clusters demonstrate substantial urea electrosynthesis activity.…”

Section: Resultsmentioning

confidence: 98%

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo₂C MXene

Zhang,

Lu,

Zhao

et al. 2024

J. Mater. Chem. A

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“…Given these factors, we conducted our calculations in a neutral state, an approach that is widely used in numerous studies. 30–33…”

Section: Structures and Computational Detailsmentioning

confidence: 99%

Enhanced urea oxidation catalysis through Ni single-atom doping on Cu₂O surfaces: a computational study

Li,

Lin,

Huang

et al. 2024

J. Mater. Chem. A

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“…[6b,9] Moreover, Liu et al proposed the adjacent *NH species or dimerized *N 2 can bond with CO molecular, resulting a superior activity for urea synthesis. [10] In this regard, the design of efficient catalysts for urea electrosynthesis is expected to be bi-functional in both CO 2 RR and NO 3 À RR. [11] However, in aqueous electrolytes, owing to the low solubility of CO 2 and the higher polarity of water molecule than CO 2 , surface sites are preferentially occupied by water, therefore, hydrogen evolution reduction (HER) is generally more preferred than CO 2 reduction, the number of catalysts capable of preferential CO 2 RR over hydrogen production (HER) is limited.…”

Section: Introductionmentioning

confidence: 99%

The Tandem Nitrate and CO₂ Reduction for Urea Electrosynthesis: Role of Surface N‐Intermediates in CO₂ Capture and Activation

Huang,

Li,

Xie

et al. 2024

Angewandte Chemie

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Electrochemical reduction of CO2 and nitrate offers a promising avenue to produce valuable chemicals through the using of greenhouse gas and nitrogen‐containing wastewater. However, the generally proposed reaction pathway of concurrent CO2 and nitrate reduction for urea synthesis requires the catalysts to be both efficient in both CO2 and nitrate reduction, thus narrowing the selection range of suitable catalysts. Herein, we demonstrate a distinct mechanism in urea synthesis, a tandem NO3‐ and CO2 reduction, in which the surface amino species generated by nitrate reduction play the role to capture free CO2 and subsequent initiate its activation. When using the TiO2 electrocatalyst derived from MIL‐125‐NH2, it intrinsically exhibits low activity in aqueous CO2 reduction, however, in the presence of both nitrate and CO2, this catalyst achieves an excellent urea yield rate of 43.37 mmol･g‐1･h‐1 and a Faradaic efficiency of 48.88% at ‐0.9 V vs. RHE in a flow cell. Even at a low CO2 level of 15%, the Faradaic efficiency of urea synthesis remains robust at 42.33%. The tandem reduction procedure was further confirmed by in‐situ spectroscopies and theoretical calculations. This research provides new insights into the selection and design of electrocatalysts for urea synthesis.

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Electrocatalytic Urea Synthesis via N₂ Dimerization and Universal Descriptor

Cited by 11 publications

References 76 publications

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo₂C MXene

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo₂C MXene

Enhanced urea oxidation catalysis through Ni single-atom doping on Cu₂O surfaces: a computational study

The Tandem Nitrate and CO₂ Reduction for Urea Electrosynthesis: Role of Surface N‐Intermediates in CO₂ Capture and Activation

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Electrocatalytic Urea Synthesis via N2 Dimerization and Universal Descriptor

Cited by 11 publications

References 76 publications

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo2C MXene

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo2C MXene

Enhanced urea oxidation catalysis through Ni single-atom doping on Cu2O surfaces: a computational study

The Tandem Nitrate and CO2 Reduction for Urea Electrosynthesis: Role of Surface N‐Intermediates in CO2 Capture and Activation

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Electrocatalytic Urea Synthesis via N₂ Dimerization and Universal Descriptor

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo₂C MXene

Efficient urea synthesis via one-step N–C–N coupling: strong metal–support interaction-driven planar Cu clusters on two-dimensional Mo₂C MXene

Enhanced urea oxidation catalysis through Ni single-atom doping on Cu₂O surfaces: a computational study

The Tandem Nitrate and CO₂ Reduction for Urea Electrosynthesis: Role of Surface N‐Intermediates in CO₂ Capture and Activation