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Cited by 59 publications
(32 citation statements)
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“…Further improvements in the electrocarboxylation processes employing redox mediators [3][4][5] and silver cathodes [6,7] have been reported. Poly halogenated aromatic compounds [8], iodo aromatic compounds [9] and aliphatic halides [10,11] also undergo facile electrocarboxylation.…”
Section: Introductionmentioning
confidence: 99%
“…Further improvements in the electrocarboxylation processes employing redox mediators [3][4][5] and silver cathodes [6,7] have been reported. Poly halogenated aromatic compounds [8], iodo aromatic compounds [9] and aliphatic halides [10,11] also undergo facile electrocarboxylation.…”
Section: Introductionmentioning
confidence: 99%
“…The electrocatalytic properties of silver have been exploited in several electrosynthetic processes, in particular the electrosynthesis of fine chemicals and pharmaceutical products by electrocarboxylation of the corresponding chlorides [16,17]. In some cases, also a first scale up has been developed with very encouraging results [18].…”
mentioning
confidence: 99%
“…CO 2 is non-toxic and can work as an electrophile in the reaction of anion species to give carboxylic acids with one carbon elongation. Electrocarboxylation has been described for a large number of substrate types, including ketones, 7,8 alkynes, 9 olefins, 10,11 alkyl halides, 12 and heterocyclic compounds. 13,14 Electrochemical carboxylation of phenyl-substituted alkenes has been reported by several workers, however, a mixture of mono-and dicarboxylated acids has been obtained, 15,16 and carboxylic acids have only been formed in low conversions by using a nickel(II) catalyst 17 or expensive Pt electrode.…”
Section: Introductionmentioning
confidence: 99%