2013
DOI: 10.1002/ange.201302882
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Abstract: Professor Werner Uhl zum 60. Geburtstag gewidmet Vor fast 150 Jahren entdeckte Bettendorff das gelbe Arsen als ein Elementallotrop. Er konnte es aber nicht in reiner Form isolieren, da es extrem instabil ist und sich schnell in eine amorphe Form zersetzt.[1] Nach 35 Jahren intensiver Diskussion über seine Existenz oder Nichtexistenz waren Erdmann und Unruh die ersten, die über die Synthese von gelbem Arsen in grçßeren Mengen und seine physikalischen Eigenschaften berichteten.[2] Jedoch bedurfte es weiterer 75 … Show more

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Cited by 27 publications
(8 citation statements)
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“…Reaction of the thorium butadiene complex (η In contrast, activation of molecular arsenic by homogeneous transition metal complexes is considerably more diverse; formation of cyclo-Asn ligands (n = 3-6, 8) [54,148], metal arsenic clusters [149], coordination of intact As4 tetrahedra to metal ions [133,150,151], fragmentation into As2 and other As4 ligands [152][153][154], catenation to As10 and As12 ligands [155], reactions to form PnAsm ligands [156], and full As4 fragmentation resulting in terminal M≡As arsenide bonds [157] have all been reported.…”
Section: Arsenic Antimony and Bismuth Activation By Rare Earth And Amentioning
confidence: 99%
“…Reaction of the thorium butadiene complex (η In contrast, activation of molecular arsenic by homogeneous transition metal complexes is considerably more diverse; formation of cyclo-Asn ligands (n = 3-6, 8) [54,148], metal arsenic clusters [149], coordination of intact As4 tetrahedra to metal ions [133,150,151], fragmentation into As2 and other As4 ligands [152][153][154], catenation to As10 and As12 ligands [155], reactions to form PnAsm ligands [156], and full As4 fragmentation resulting in terminal M≡As arsenide bonds [157] have all been reported.…”
Section: Arsenic Antimony and Bismuth Activation By Rare Earth And Amentioning
confidence: 99%
“…Die derart stabilisierten As4‐Tetraeder stehen für weitere Umsetzung zur Verfügung sodass mit dem Silbersalz ein effizientes As4‐Transferreagenz zur Verfügung steht. Die As4‐Einheiten lassen sich auf Gold(I)‐Verbindungen (53) übertragen106 und koordinieren terminal im γ1‐Modus an [Cp*(dppe)Ru]+ (54) 107…”
Section: Gruppe 15unclassified
“…In such complexes,t he basal phosphorus atoms of thec age coordinate to them etal atom, or as in dimeric [{Ru(Cp)(PPh 3 ) 2 } 2 P 4 S 3 ] 2 + ,t he nortricyclane cage interacts with the metal fragments through the apical as well as one of the basal phosphorus atoms. [6,7] These complexes can enable interesting degradationchemistry of the otherwise inert cages under standard conditions. [6,7] These complexes can enable interesting degradationchemistry of the otherwise inert cages under standard conditions.…”
Section: Introductionmentioning
confidence: 99%
“…The hydrolysis of [{CpRu(PPh 3 ) 3 } 2 (P 4 )] 2 + and [{CpRu(PPh 3 ) 3 } 2 (P 4 S 3 )] 2 + salts, for example, yield complexes of diphosphane and thiophosphinic acid. [7,8] In this realm, the more electron-poor complex [CpFe(CO) 2 ] + (Fp + )a nd monophosphine-substituted complex [CpFe-(CO)(PPh 3 )] + (FpPPh 3 + )u nits are not knownf or coordination chemistry that uses such weak ligands. Thus, Scheeretal.…”
Section: Introductionmentioning
confidence: 99%
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