2007
DOI: 10.1002/chin.200740141
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G. Alex Cortez,
Richard R. Schrock,
Amir H. Hoveyda

Abstract: The chiral adamantylimido molybdenum complex AMO efficiently catalyzes the title reaction of a range of N-substituted unsaturated azabicycles with styrenes to give 2,6-dialkenylpiperidines, in general, with high enantioselectivities and with >98% (E)-selectivity in all cases. To minimize the formation of product-derived homodimers, the reactions are performed with a large excess of the styrene. The reactions of bicycles (VIII) in the presence of ruthenium catalyst IRU proceed with higher conversions (90%) tha…

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