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Effect of Solvents on the Thermal Isomerization of 1α-Hydroxyprevitamin D3 Diacetate to 1α-Hydroxyvitamin D3 Diacetate
Abstract: SummaryThe thermal conversion of 1ƒ¿-hydroxyprevitamin D3 (1ƒ¿-
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Cited by 4 publications
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“…902 (Similarly, an enhanced rate of conversion for 1 -hydroxyprevitamin D 3 diacetate in benzene as compared with other solvents is not easily explained. 903 ) Substitution of the 3-hydroxy group in previtamin D 2 by electron-withdrawing groups shifts the equilibrium to the previtamin side, which has been explained in terms of *interactions. 904 Thermal rearrangement of an unnatural (7Z) form of vitamin D has also been studied.…”
Section: Biosynthesis Of Vitamin D and Bile Acidsmentioning
confidence: 99%
“…902 (Similarly, an enhanced rate of conversion for 1 -hydroxyprevitamin D 3 diacetate in benzene as compared with other solvents is not easily explained. 903 ) Substitution of the 3-hydroxy group in previtamin D 2 by electron-withdrawing groups shifts the equilibrium to the previtamin side, which has been explained in terms of *interactions. 904 Thermal rearrangement of an unnatural (7Z) form of vitamin D has also been studied.…”
Section: Biosynthesis Of Vitamin D and Bile Acidsmentioning
confidence: 99%
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