1989
DOI: 10.1111/j.1365-2621.1989.tb05972.x
|View full text |Cite
|
Sign up to set email alerts
|

Effect of Methyl Ester Content on Heat Degradation of Chelator‐Soluble Carrot Pectin

Abstract: Chelator-soluble pectin was isolated from carrot under mild conditions and used as a model compound for an investigation of the heat degradation mechanism of pectin in an aqueous environment. Methyl ester content was modified with minimal changes in the polymer size. At pH 6.1 the heated pectin preparation degraded primarily through p-eliminative cleavage of the chain. The higher the methyl ester content the greater the degradation. Evidences also indicated a.small amount of hydrolytic cleavage of glycosidic b… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

2
73
1

Year Published

1997
1997
2017
2017

Publication Types

Select...
9

Relationship

0
9

Authors

Journals

citations
Cited by 122 publications
(78 citation statements)
references
References 35 publications
2
73
1
Order By: Relevance
“…Changes in the cell wall compartment were fairly limited; this may be linked to the pH, which was close to that of maximum stability of pectins, 8,59 rather than to the intrinsic properties of the pear pectins, to the structure of the cell walls or to the presence of a high proportion of stone cells with their secondary cell walls (and high xylose content). The proportion of AIS, usually taken to be representative of the cell wall, actually increased early in the cooking.…”
Section: Discussionmentioning
confidence: 99%
“…Changes in the cell wall compartment were fairly limited; this may be linked to the pH, which was close to that of maximum stability of pectins, 8,59 rather than to the intrinsic properties of the pear pectins, to the structure of the cell walls or to the presence of a high proportion of stone cells with their secondary cell walls (and high xylose content). The proportion of AIS, usually taken to be representative of the cell wall, actually increased early in the cooking.…”
Section: Discussionmentioning
confidence: 99%
“…177 Third, demethoxylation of pectin reduces its sensitivity to chemical b-eliminative depolymerisation, occurring during heating and associated with heat-induced softening of many fruits and vegetables. 87,178,179 Thus, a reduction in DM by PME stimulation through pretreatment has a second texture-conserving effect, reducing the vulnerability to thermal softening.…”
Section: Pme In Relation To Texture Of Plant-based Foodsmentioning
confidence: 98%
“…Table 4 shows changes in the relative content of WSP during steaming show that the b-elimination reaction was involved in increasing the WSP content with increasing steaming time. It is known that the higher the methyl ester content, the greater the degradation of pectic substances by the b-elimination reaction (Sajjaanantakul et al, 1989). We reasoned that because of a decrease in esterification rates of pectic substances in tea leaves harvested during the fallwinter crop season, the degree of increase in the WSP content by steaming for that crop season was lower than for the first and second crop seasons.…”
Section: Determination Of the Degree Of Methylation (Dm) Of Pecticmentioning
confidence: 92%