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Cited by 11 publications
(2 citation statements)
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References 30 publications
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“…Many recent studies focused on the hydroconversion of decalin in the context of selective ring opening, i.e., with a bifunctional catalyst with very high metal loadings, having a high hydrogenolysis activity. Under such conditions, the metal assumes a cracking function that is beneficial for the purpose of selective ring opening of compounds like decaline. Here, we only consider bifunctional catalysts where the metal function only serves hydrogenation–dehydrogenation to feed the acid sites with olefins. Hydrocracking studies of this kind have been dealing with naphthenes presenting three cycles, two cycles, or one cycle. It has been shown that the hydroisomerization and hydrocracking mechanisms of cyclic molecules follow similar principles as for the hydroconversion of alkanes with respect to relative stabilities of involved alkylcarbenium ions, but the presence of rings leads to distinctly different product distributions .…”
Section: Introductionmentioning
confidence: 99%
“…Many recent studies focused on the hydroconversion of decalin in the context of selective ring opening, i.e., with a bifunctional catalyst with very high metal loadings, having a high hydrogenolysis activity. Under such conditions, the metal assumes a cracking function that is beneficial for the purpose of selective ring opening of compounds like decaline. Here, we only consider bifunctional catalysts where the metal function only serves hydrogenation–dehydrogenation to feed the acid sites with olefins. Hydrocracking studies of this kind have been dealing with naphthenes presenting three cycles, two cycles, or one cycle. It has been shown that the hydroisomerization and hydrocracking mechanisms of cyclic molecules follow similar principles as for the hydroconversion of alkanes with respect to relative stabilities of involved alkylcarbenium ions, but the presence of rings leads to distinctly different product distributions .…”
Section: Introductionmentioning
confidence: 99%
“…However, conversion values up to 52% have been reported by Santi et al using a 3.5Ir/Rb, H‐Beta catalyst. Another substantial disadvantage for its industrial application is catalyst deactivation by coke deposition and sulfur poisoning …”
Section: Introductionmentioning
confidence: 99%