AlGaN/GaN high electron mobility transistors (HEMTs) were demonstrated for structures grown on ZrTi metallic alloy buffer layers, which provided lattice matching of the in-plane lattice parameter ("a-parameter") to hexagonal GaN. The quality of the GaN buffer layer and HEMT structure were confirmed with X-ray 2θ and rocking scans as well as cross-section transmission electron microscopy (TEM) images. The X-ray 2θ scans showed full widths at half maximum (FWHM) of 0.06 • , 0.05 • and 0.08 • for ZrTi alloy, GaN buffer layer, and the entire HEMT structure, respectively. TEM of the lower section of the HEMT structure containing the GaN buffer layer and the AlN/ZrTi/AlN stack on the Si substrate showed that it was important to grow AlN on the top of ZrTi prior to growing the GaN buffer layer. The estimated threading dislocation (TD) density in the GaN channel layer of the HEMT structure was in the 10 8 cm −2 range. AlGaN/GaN high electron mobility transistors (HEMTs) show great promise for high power and high frequency applications such as inverter units in hybrid electric vehicles, advanced radar systems, and satellite-based communication networks, due to their high sheet carrier concentration, high electron mobility, and radiation hardness. [1][2][3][4][5] In order to lower the cost of HEMTs, larger diameter substrates are needed. Currently, HEMT structures are grown on non-native sapphire, SiC and Si substrates or on native substrates of vapor phase epitaxy (VPE) GaN wafers. [4][5][6] HEMTs grown on sapphire substrates suffer from poor heat dissipation and higher defect density due to the relative larger lattice mismatch to GaN. SiC has very good thermal conductivity and has less lattice mismatch to GaN, but high quality semi-insulating SiC substrates are quite expensive. Although Si substrates have fairly low cost and are available in larger diameters, the greater lattice mismatch to GaN requires the growth of thick AlGaN buffers prior to GaN growth to reduce the threading dislocation density.7-9 These thick AlGaN layers are usually defective and thermally resistive, which hinders device heat dissipation. Free-standing VPE-grown GaN wafers are currently limited to 2-3 diameter and are very expensive. Recently, it was reported that high quality GaN layers could be grown by RF plasma-assisted molecular beam epitaxy (PA-MBE) or metal-organic chemical vapor deposition (MOCVD) on high-quality, single-crystal ZrTi refractory metal alloys deposited by plasma sputtering on c-plane sapphire and Si substrates.10 These ZrTi refractory metal alloys are not only lattice-matched to GaN, but have similar coefficient of thermal expansion (CTE) to that of GaN. 10 By employing these ZrTi alloys as buffer layers, there is no need to grow thick AlGaN buffers, potentially allowing both photonic and electronic GaN-based device structure to be grown on large-area Si substrates, hence reducing the cost of device fabrication. AlGaN/GaN HEMT grown on sapphire with ZrTi alloys as buffer layers has been demonstrated.
11In this work, we...