TiO 2 @MWCNT heterostructure containing single one carbon nanotube has been successfully prepared via solvothermal method. X-ray di®ration (XRD) analysis shows that TiO 2 nanocrystals only contain highly crystallized tetragonal anatase phase. Interestingly, scanning electron microscope (SEM) and transmission electron microscope (TEM) results show that most of the TiO 2 nanocrystals are perpendicular to the surface of multi-walled carbon nanotube (MWCNT) and only single one carbon nanotube is coated by TiO 2 crystals. The electromagnetic (EM) characteristics are investigated at 0.5-18.0 GHz range. The EM properties show that both the permittivity and the permeability present a typical resonance behavior at 11.0 GHz and 12.0 GHz, respectively. Besides, the TiO 2 @MWCNT heterostructures exhibit a broadband absorption throughout the whole Ku wave bands (12.0-18.0 GHz) Interestingly, the re°ection loss (RL) of the TiO 2 @MWCNT heterostructures change slightly as the thickness of the heterostructures increase from 3.0 mm to 5.0 mm in the 8.0-13.0 GHz range.