In this paper, we apply a reconstructed higher-order compact scheme on nonuniform grids to the problem of double-diffusive natural convection in a vertical porous annulus. The Darcy model is adopted for the fluid flow h c h c ). Furthermore, the top and bottom boundaries of the cavity are adiabatic and impermeable.The following assumptions hold for this study:(i) Darcy's law is applicable in the porous medium.(ii) The porous matrix is uniform and in equilibrium with the fluid.