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Cited by 16 publications
(5 citation statements)
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“…Analysis of literature data concerning isomerization of double bond in unsaturated hydrocarbons and alcohols showed that supported noble metals provide sufficient selectivity in this process [4,7,[15][16][17]. However, experiments carried out with isoprenol in the range of 75-90 8C in the stream of H 2 on silica supported Pd, Pt, Ru and Ir catalysts led to the preferred hydrogenation of double bond.…”
Section: Resultsmentioning
confidence: 85%
“…Analysis of literature data concerning isomerization of double bond in unsaturated hydrocarbons and alcohols showed that supported noble metals provide sufficient selectivity in this process [4,7,[15][16][17]. However, experiments carried out with isoprenol in the range of 75-90 8C in the stream of H 2 on silica supported Pd, Pt, Ru and Ir catalysts led to the preferred hydrogenation of double bond.…”
Section: Resultsmentioning
confidence: 85%
“…Amines also play an important role in modifying the selectivity and activity of other catalytic reactions. For example, palladium [20] and ruthenium [21] based hydrogenation catalysts are enhanced by amine modification and the enantioselective hydrogenation of a-functionalised ketones and olefins over platinum [22] requires a modifier containing a basic nitrogen atom [23][24][25][26] and the presence of oxygen [27].…”
Section: Introductionmentioning
confidence: 99%
“…Amines have applications in many interface related areas including corrosion inhibition, adhesion, and heterogeneous catalysis. , In the latter case, amines are commonly used not only as reactants but also as catalyst modifiers. Pfaltz, for example, has shown that a basic nitrogen group is a necessary component of chiral modifiers for the hydrogenation of α-functionalized ketones. The interaction of the amine functionality with the surface is therefore a subject of some importance in surface science. Our own interest in amine surface chemistry stems from studies of ammonia oxidation and of the interaction of pyridine with surface oxygen, where intermolecular complexes between pyridine and both molecular oxygen transients and chemisorbed atomic oxygen , have been demonstrated.…”
Section: Introductionmentioning
confidence: 99%