2017
DOI: 10.1038/srep43706
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Abstract: A series of ABA triblock copolymers, consisting of double-bond-containing poly(phenoxyallene) (PPOA), poly(methyl methacrylate) (PMMA), or poly(butyl acrylate) (PBA) segments, were synthesized by sequential free radical polymerization and atom transfer radical polymerization (ATRP). A new bifunctional initiator bearing azo and halogen-containing ATRP initiating groups was first prepared followed by initiating conventional free radical homopolymerization of phenoxyallene with cumulated double bond to give a PPO… Show more

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Cited by 7 publications
(2 citation statements)
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References 55 publications
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“…Using a similar strategy, the same group synthesized well-defined PEG- b -PDMAEMA- b -PMPC. Huang and coworkers synthesized a series of ABA triblock copolymers, consisting of double-bond-containing poly(phenoxyallene) (PPOA), PMMA, or PBA segments using sequential free radical polymerization and ATRP [ 30 ]. A bifunctional initiator bearing azo and halogen-containing ATRP initiating groups was first used to initiate the conventional free radical homopolymerization of phenoxyallene with a cumulated double bond to give a PPOA-based macroinitiator with ATRP-initiating groups at both ends.…”
Section: Synthesis Of Bcpsmentioning
confidence: 99%
See 1 more Smart Citation
“…Using a similar strategy, the same group synthesized well-defined PEG- b -PDMAEMA- b -PMPC. Huang and coworkers synthesized a series of ABA triblock copolymers, consisting of double-bond-containing poly(phenoxyallene) (PPOA), PMMA, or PBA segments using sequential free radical polymerization and ATRP [ 30 ]. A bifunctional initiator bearing azo and halogen-containing ATRP initiating groups was first used to initiate the conventional free radical homopolymerization of phenoxyallene with a cumulated double bond to give a PPOA-based macroinitiator with ATRP-initiating groups at both ends.…”
Section: Synthesis Of Bcpsmentioning
confidence: 99%
“… Synthesis of polyallene-based triblock copolymer using conventional free radical and ATRP. Reprinted from Reference [ 30 ]. (Copyright (2017) Nature Publishing Group).…”
Section: Figures and Schemesmentioning
confidence: 99%