Dispersive Micro-solid Phase Extraction with Fibrous TiO2@g- C3N4 Nanocomposites Coupled with ICP-MS for the Determination of Cobalt and Nickel in Environmental and Biological Samples

Abstract

In this work, fibrous TiO2@g-C3N4 nanocomposites (FTGCNCs) were used for dispersive micro-solid phase extraction of Co and Ni prior to their determination by inductively coupled plasma mass spectrometry. As a new adsorbent, the surface on FTGCNCs have rich functional groups such as-NH2,-NH-and =N-, which can selectively adsorb target ions. The adsorption behaviors of Co and Ni on FTGCNCs were investigated. The results indicated that the analytes were quantitatively retained on FTGCNCs in the pH range of 5.0-8.…