volume 6, issue 68, P63519-63524 2016
DOI: 10.1039/c6ra09619k
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Abstract: Dispersion polymerization of acrylamide (AM) catalyzed by cobalt porphyrin [Cobalt tetramethoxyphenylporphyrin, (TMOP)Co(II)] with the feature of living radical polymerization (LRP) in alcohol/water or dimethylformamide (DMF)/water was described. Well-defined polyacrylamide (PAM) uniform spherical particles with predetermined molecular weight and narrow polydispersity (Mw/Mn = 1.09-1.35) were obtained under mild thermal conditions. Linear first-order kinetics with different feeding ratio of AM and cobalt porp…

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