Discovery of Cadinane-Type Sesquiterpenoids from the Infected Stems of Hibiscus tiliaceus as Potential Agrochemical Fungicides
Deli Chen,
Xudong Xu,
Yun Yang
et al.
Abstract:Ten new cadinane-type sesquiterpenoids, named hibisceusins I−R (1−10), along with 14 known sesquiterpenoids (11−24), were acquired from the tainted stems of Hibiscus tiliaceus. Their structures were identified via spectroscopic analysis, onedimensional (1D) and two-dimensional (2D) NMR, and computer-assisted structure elucidation techniques, including infrared (IR) and mass spectrometry (MS) data. Additionally, subsequent DP4/DP4+ probability methods were used to resolve 3′s relative configurations by comparin… Show more
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