Directly using H2S to Synthesize Crystalline Poly(thioether‐ester)s via Organocatalysis
Ziheng Liu,
Yanni Xia,
Wenqi Guo
et al.
Abstract:The direct utilization of H2S in polymerization is rarely reported. Here we report step polymerization of H2S and diacrylates using commercially available organic bases as the catalysts. Poly(thioether‐ester)s were successfully synthesized in atom‐economical way, as confirmed by 1H NMR spectra, and the molecular weights of these poly(thioether‐ester)s could be up to 64.7 kDa as determined by the gel permeation chromatography, which also shows the polymerization of H2S with diacrylates is stepwise manner. The c… Show more
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