Direct deposition of graphene nanowalls on ceramic powders for the fabrication of a ceramic matrix composite*

Abstract

Uniform mixing of ceramic powder and graphene is of great importance for producing ceramic matrix composite. In this study, graphene nanowalls (GNWs) are directly deposited on the surface of Al2O3 and Si3N4 powders using chemical vapor deposition system to realize the uniform mixing. The morphology and the initial stage of the growth process are investigated. It is found that the graphitic base layer is initially formed parallel to the powder surface and is followed by the growth of graphene nanowalls perpendicular to the surface. Moreover, the lateral length of the graphene sheet could be well controlled by tuning the growth temperature. GNWs/Al2O3 powder is consolidated by using sparking plasma sintering method and several physical properties are measured. Owing to the addition of GNWs, the electrical conductivity of the bulk alumina is significantly increased.