Diamines as auxiliary ligands for tuning photophysical and electrochemical properties of Ruthenium(II) polypyridyl complexes

Al-Rashdi, Kamelah S.; Babgi, Bandar A.; Şahın, Çiğdem; Eltayeb, Naser Eltaher; Moxey, Graeme J.; Humphrey, Mark G.

doi:10.1016/j.molstruc.2018.01.026

Cited by 4 publications

(1 citation statement)

References 33 publications

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“…Solvents and reagents were purchased from commercial vendors and were used without further purification. The amine-based reduced organic cages were prepared according to previously reported experimental procedures. , Ru(bipy) 2 Cl 2 , [Ru(bipy) 2 (eda)]Cl 2 , and (tmeda)CoCl 2 were prepared with minor modifications as described in the literature. − …”

Section: Methodsmentioning

confidence: 99%

Stabilizing Porosity in Organic Cages through Coordination Chemistry

et al. 2021

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The number of studies concerning the permanent porosity of molecular materials, especially porous organic cages (POCs) and porous coordination cages (PCCs), have increased substantially over the past decade. The work presented here outlines novel approaches to the preparation of porous molecular structures upon metalation of nonporous, amine-based organic cages. Reduction of the well-known CC3 and CC1 imine-based POCs affords nonporous, highly flexible amine cages. These materials can be endowed with significant levels of structural rigidity via post-synthetic metalation of their ethylenediamine-type binding pockets. The hybrid metal−organic cages accessed through this approach combine aspects of POC and PCC chemistry, with structures of this type providing a potentially promising new direction for the design and development of porous molecular materials with tunability in overall charge, metal cation, porosity, and solubility.

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