Based on previously discovered forbidden values of the c/a ratio, we studied anomalies in the temperature evolution of the lattice parameters (a, c) of several hexagonal RTAl compounds at high temperatures (above room temperature). The compound ErNi 0.45 Cu 0.55 Al, that seemed to be impossible to be prepared in single-phase form, reaches the single-phase state at temperatures above 493 K (220 • C). On the other hand, the compound TbNi 0.7 Cu 0.3 Al -that was expected to undergo a first-order structural phase transition at high temperatures -exhibits a second-order type transition when approaching the critical values of the c/a ratio. These results are in agreement with idea of a forbidden range of c/a values in these compounds.PACS numbers: 61.50.Ks, 61.05.cp
IntroductionFor several RTAl compounds (R = rare earth; T = transition metal) crystallizing in the hexagonal ZrNiAl-type of structure, an anomalous behavior of the lattice parameters has been observed. A step in the temperature and composition dependence of the lattice constants a and c is present in many of these compounds (e.g. TbNiAl We have studied several compounds exhibiting this type of transition at high temperatures up to ≈ 1270 K (900• C) in order to check the possibility of the isostructural transition at high temperatures. We have focused particularly on the ErNi 0.45 Cu 0.55 Al and TbNi 0.7 Cu 0.3 Al compounds for their specific properties.Polycrystalline samples were prepared by a standard arc-melting process under Ar-protective atmosphere starting from a stoichiometric composition of the pure elements. The ingots were pulverized, and then checked by means of