2009
DOI: 10.1016/j.fuel.2009.02.025
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Development of low-cost biomass-based adsorbents for postcombustion CO2 capture

Abstract: In this work a series of carbon adsorbents were prepared from a low-cost biomass residue, olive stones. Two different approaches were studied: activation with CO 2 and heat treatment with gaseous ammonia. The results showed that both methods are suitable for the production of adsorbents with a high CO 2 adsorption capacity, and their potential application in VSA or TSA systems for postcombustion CO 2 capture. It was found that the presence of nitrogen functionalities enhances CO 2 adsorption capacity, especial… Show more

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Cited by 191 publications
(120 citation statements)
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References 37 publications
(53 reference statements)
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“…Adsorption on carbonaceous material is favored at high partial pressure of adsorbate. Hence, the CO 2 capture capacity in a real industrial process, where CO 2 is diluted with other flue gases, will be lower than achieved in pure CO 2 in laboratory work (Arenillas et al 2005;Plaza et al 2009). To increase adsorption capacity for carbonaceous materials, different modifications can be made through physical or chemical processes.…”
Section: Carbonaceous Material-based Adsorbentsmentioning
confidence: 96%
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“…Adsorption on carbonaceous material is favored at high partial pressure of adsorbate. Hence, the CO 2 capture capacity in a real industrial process, where CO 2 is diluted with other flue gases, will be lower than achieved in pure CO 2 in laboratory work (Arenillas et al 2005;Plaza et al 2009). To increase adsorption capacity for carbonaceous materials, different modifications can be made through physical or chemical processes.…”
Section: Carbonaceous Material-based Adsorbentsmentioning
confidence: 96%
“…These processes have been examined for CO 2 capture at pilot-scale, but this technique is costly, requires pre-treatment, and produces large amount of wastewater and sludge. In adsorption process, the added advantages of those solid adsorbents are easy to handle and do not give rise to corrosion problems (Plaza et al 2009;Thiruvenkatachari et al 2009). …”
Section: Co 2 Capture Technologiesmentioning
confidence: 99%
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“…Nevertheless, the chemisorption process is ineffective at lower temperature and thus, causes poor CO 2 adsorption capacity. The importance of the surface area in the physisorption process can be proved by comparing the sorption capacity of the prepared activated capacity in the study with the activated olive stone char [1]. Referring to the higher surface area possessed by the physically-CO 2 activated olive stone char with the synthesized and the commercial adsorbent used in this study; it contributes to more adsorption capacity than the utilized activated carbons in this work.…”
Section: B Carbon Dioxide Adsorption Performancementioning
confidence: 85%
“…Associated with that, carbon dioxide (CO 2 ) is labeled as the most important GHGs that contribute to the global warming through anthropogenic emission from power plant generation, transportation, and industrial sector [1]. Instead of adapting to the substantial effect of global warming, mitigation of the CO 2 emission is preferable.…”
Section: Introductionmentioning
confidence: 99%