Pd-functionalized β-Bi 2 O 3 nanowires are synthesized by thermal evaporation of Bi powder using VLS mechanism followed by Pd coating and annealing. In this study, sensing properties of Pd-functionalized β-Bi 2 O 3 nanowires sensor to selected concentrations of NO 2 gas were examined. Scanning electron microscopy showed that the nanowires with diameters in a range of 100 -200 nm and lengths of up to a few tens of micrometers. Transmission electron microscopy and X-ray diffraction confirmed that the products corresponded to the nanowires of β-Bi 2 O 3 crystals and Pd nanoparticles. Pd-functionalized β-Bi 2 O 3 nanowires sensor showed an enhanced sensing performance to NO 2 gas compared to as-synthesized β-Bi 2 O 3 nanowires sensor. As synthesized and Pd-functionalized β-Bi 2 O 3 nanowire sensors showed responses of 178% -338% and 196% -535% at 300 o C, respectively, to 0.05 -2 ppm NO 2 . In addition, the underlying mechanism of the enhancement of the sensing properties of β-Bi 2 O 3 nanowires by Pd-functionalization is discussed.